Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol | Sciact - CRIS-система Института катализа

Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol Научная публикация

Журнал

Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045

Вых. Данные

Год: 2017, Том: 56, Номер: 45, Страницы: 13240-13253 Страниц : 14 DOI: 10.1021/acs.iecr.7b01636

Ключевые слова

OXYGENATED HYDROCARBONS; CATALYSTS; ALKANES

Авторы

Murzin Dmitry Yu. ¹ , Garcia Sonia ² , Russo Vincenzo ^1,3 , Kilpiö Teuvo ¹ , Godina Lidia I. ¹ , Tokarev Anton V. ¹ , Kirilin Alexey V. ¹ , Simakova Irina L. ⁴ , Poulston Stephen ² , Sladkovskii Dmitry A. ⁵ , Warna Johan ¹

Организации

1	Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland
2	Johnson Matthey Technology Centre, Sonning Common, Reading RG4 9NH, UK
3	Universita degli Studi di Napoli “Federico II”, 80138, Naples, Italy
4	Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia
5	St. Petersburg State Institute of Technology (Technical University), St. Petersburg, 190013, Russia

Информация о финансировании (2)

1	European Commission	310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT
2	Министерство образования и науки Российской Федерации	14.Z50.31.0013

The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modelling a complex reaction network was taken into account considering formation not only hydrogen and CO2, but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. Influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated combusting alkanes formed during APR reaction.

Murzin D.Y. , Garcia S. , Russo V. , Kilpiö T. , Godina L.I. , Tokarev A.V. , Kirilin A.V. , Simakova I.L. , Poulston S. , Sladkovskii D.A. , Warna J.
Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol
Industrial and Engineering Chemistry Research. 2017. V.56. N45. P.13240-13253. DOI: 10.1021/acs.iecr.7b01636 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	18 апр. 2017 г.
Принята к публикации:	30 июн. 2017 г.
Опубликована online:	14 июл. 2017 г.
Опубликована в печати:	15 нояб. 2017 г.

Web of science:	WOS:000415785500037
Scopus:	2-s2.0-85034043817
РИНЦ:	31053390
Chemical Abstracts:	2017:1100388
Chemical Abstracts (print):	167:531729
OpenAlex:	W2728062393

БД	Цитирований
Web of science	24
Scopus	27
РИНЦ	28
OpenAlex	28