Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol Full article

Journal

Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045

Output data

Year: 2017, Volume: 56, Number: 45, Pages: 13240-13253 Pages count : 14 DOI: 10.1021/acs.iecr.7b01636

Tags

OXYGENATED HYDROCARBONS; CATALYSTS; ALKANES

Authors

Murzin Dmitry Yu. ¹ , Garcia Sonia ² , Russo Vincenzo ^1,3 , Kilpiö Teuvo ¹ , Godina Lidia I. ¹ , Tokarev Anton V. ¹ , Kirilin Alexey V. ¹ , Simakova Irina L. ⁴ , Poulston Stephen ² , Sladkovskii Dmitry A. ⁵ , Warna Johan ¹

Affiliations

1	Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University, FI-20500 Turku/Åbo, Finland
2	Johnson Matthey Technology Centre, Sonning Common, Reading RG4 9NH, UK
3	Universita degli Studi di Napoli “Federico II”, 80138, Naples, Italy
4	Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia
5	St. Petersburg State Institute of Technology (Technical University), St. Petersburg, 190013, Russia

Funding (2)

1	European Commission	310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT
2	The Ministry of Education and Science of the Russian Federation	14.Z50.31.0013

The present study was focused on kinetic investigation of xylitol aqueous phase reforming with 2.5%Pt/C catalyst in a fixed bed reactor. For kinetic modelling a complex reaction network was taken into account considering formation not only hydrogen and CO2, but also a range of alkanes in various side reactions. Parameter investigation revealed an adequate description of the experimental data. Influence of mass transfer was elucidated by exploring the parameter space of diffusion and mass transfer coefficients as well as Peclet numbers. Aspen HYSYS software was used to design a hydrogen production plant with 500 kg/h capacity operating with xylitol as a feedstock. Heat consumption of the designed process can be fully covered by heat generated combusting alkanes formed during APR reaction.

Murzin D.Y. , Garcia S. , Russo V. , Kilpiö T. , Godina L.I. , Tokarev A.V. , Kirilin A.V. , Simakova I.L. , Poulston S. , Sladkovskii D.A. , Warna J.
Kinetics, Modeling, and Process Design of Hydrogen Production by Aqueous Phase Reforming of Xylitol
Industrial and Engineering Chemistry Research. 2017. V.56. N45. P.13240-13253. DOI: 10.1021/acs.iecr.7b01636 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Apr 18, 2017
Accepted:	Jun 30, 2017
Published online:	Jul 14, 2017
Published print:	Nov 15, 2017

Web of science:	WOS:000415785500037
Scopus:	2-s2.0-85034043817
Elibrary:	31053390
Chemical Abstracts:	2017:1100388
Chemical Abstracts (print):	167:531729
OpenAlex:	W2728062393

DB	Citing
Web of science	24
Scopus	27
Elibrary	28
OpenAlex	28