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Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO Научная публикация

Журнал Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875
Вых. Данные Год: 2005, Том: 279, Страницы: 99-107 Страниц : 9 DOI: 10.1016/j.apcata.2004.10.017
Ключевые слова Cis-trans isomerization, Kinetics, Partial hydrogenation, Pd/MgO
Авторы Deliy I.V. 1 , Maksimchuk N.V. 1 , Psaro R. 2 , Ravasio N. 2 , Dal Santo V. 2 , Recchia S. 3 , Paukshtis E.A. 1 , Golovin A.V. 1 , Semikolenov V.A. 1
Организации
1 Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Homogeneous and Coordination Catalysis, Novosibirsk 630090, Russia
2 ISTM-CNR, Via C. Golgi, 19-20133 Milano, Italy
3 Dipartimento di Scienze Chimiche, Fisiche e Matematiche, Universita` dell’Insubria-Sede di Como, Via Lucini, 3-22100 Como, Italy

Информация о финансировании (2)

1 Civilian Research and Development Foundation NO-008-X1
2 Президиум РАН 9

Реферат: Kinetic peculiarities of cis and trans methyl oleate formation in the course of methyl linoleate hydrogenation over Pd/MgO were studied. Liquid phase hydrogenation was carried out in temperature range of 303–323 K and under hydrogen pressure within 1–10 bar. Gas–liquid chromatography, IR and 13C NMR techniques were employed to characterize the reaction products. Effects of hydrogen pressure and reaction temperature on cis and trans methyl oleate formation were studied. The general kinetic scheme and reaction mechanism of methyl linoleate hydrogenation and cis–trans methyl oleate isomerization have been proposed.
Библиографическая ссылка: Deliy I.V. , Maksimchuk N.V. , Psaro R. , Ravasio N. , Dal Santo V. , Recchia S. , Paukshtis E.A. , Golovin A.V. , Semikolenov V.A.
Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO
Applied Catalysis A: General. 2005. V.279. P.99-107. DOI: 10.1016/j.apcata.2004.10.017 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 14 июл. 2004 г.
Принята к публикации: 15 окт. 2004 г.
Опубликована online: 25 нояб. 2004 г.
Опубликована в печати: 28 янв. 2005 г.
Идентификаторы БД:
Web of science: WOS:000226759300010
Scopus: 2-s2.0-11944253554
РИНЦ: 13494703
Chemical Abstracts: 2005:45681
Chemical Abstracts (print): 142:299800
OpenAlex: W1972140515
Цитирование в БД:
БД Цитирований
Web of science 22
Scopus 24
РИНЦ 24
OpenAlex 23
Альметрики: