Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO | Sciact - CRIS-system of Boreskov Institute of Catalysis

Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO Full article

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2005, Volume: 279, Pages: 99-107 Pages count : 9 DOI: 10.1016/j.apcata.2004.10.017

Tags

Cis-trans isomerization, Kinetics, Partial hydrogenation, Pd/MgO

Authors

Deliy I.V. ¹ , Maksimchuk N.V. ¹ , Psaro R. ² , Ravasio N. ² , Dal Santo V. ² , Recchia S. ³ , Paukshtis E.A. ¹ , Golovin A.V. ¹ , Semikolenov V.A. ¹

Affiliations

1	Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Homogeneous and Coordination Catalysis, Novosibirsk 630090, Russia
2	ISTM-CNR, Via C. Golgi, 19-20133 Milano, Italy
3	Dipartimento di Scienze Chimiche, Fisiche e Matematiche, Universita` dell’Insubria-Sede di Como, Via Lucini, 3-22100 Como, Italy

Funding (2)

1	Civilian Research and Development Foundation	NO-008-X1
2	Президиум РАН	9

Kinetic peculiarities of cis and trans methyl oleate formation in the course of methyl linoleate hydrogenation over Pd/MgO were studied. Liquid phase hydrogenation was carried out in temperature range of 303–323 K and under hydrogen pressure within 1–10 bar. Gas–liquid chromatography, IR and 13C NMR techniques were employed to characterize the reaction products. Effects of hydrogen pressure and reaction temperature on cis and trans methyl oleate formation were studied. The general kinetic scheme and reaction mechanism of methyl linoleate hydrogenation and cis–trans methyl oleate isomerization have been proposed.

Deliy I.V. , Maksimchuk N.V. , Psaro R. , Ravasio N. , Dal Santo V. , Recchia S. , Paukshtis E.A. , Golovin A.V. , Semikolenov V.A.
Kinetic Peculiarities of Cis/Trans Methyl Oleate Formation During Hydrogenation of Methyl Linoleate over Pd/MgO
Applied Catalysis A: General. 2005. V.279. P.99-107. DOI: 10.1016/j.apcata.2004.10.017 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 14, 2004
Accepted:	Oct 15, 2004
Published online:	Nov 25, 2004
Published print:	Jan 28, 2005

Web of science:	WOS:000226759300010
Scopus:	2-s2.0-11944253554
Elibrary:	13494703
Chemical Abstracts:	2005:45681
Chemical Abstracts (print):	142:299800
OpenAlex:	W1972140515

DB	Citing
Web of science	22
Scopus	24
Elibrary	24
OpenAlex	24