Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst | Sciact - CRIS-система Института катализа

Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst Научная публикация

Конференция

6th International Conference on Material Science and Engineering Technology
20-22 окт. 2017 , Seoul

Сборник

Material Science and Engineering Technology VI : Selected papers presented at 6th International Conference on Material Science and Engineering Technology (ICMSET 2017), October 20-22, 2017, Seoul National University, Seoul, Korea
Сборник, 2018. 368 c. ISBN 978-3-0357-1213-1.

Журнал

Materials Science Forum
ISSN: 0255-5476 , E-ISSN: 1662-9752

Вых. Данные

Год: 2018, Том: 917, Страницы: 122-126 Страниц : 5 DOI: 10.4028/www.scientific.net/MSF.917.122

Ключевые слова

1,2-dichloroethane, Bulk alloys, Carbon erosion, Carbon fibers, Catalytic chemical vapor deposition, CFC-12, Halogenated hydrocarbons, Nichrome

Авторы

Bauman Yurii ¹ , Mishakov Ilya ^1,2 , Korneev Denis ³ , Vedyagin Aleksey ^1,2

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
2	National Research Tomsk Polytechnic University, Tomsk, 634050, Russia
3	State Research Center of Virology and Biotechnology ‘‘Vector’’, 630559, Koltsovo, Russia

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2015-0004
2	Министерство образования и науки Российской Федерации	VIU-TOVPM-316/2017

The way to produce the nanostructured carbon filaments via H2-assisted catalytic decomposition of CF2Cl2 over self-organizing Ni-based catalyst has been reported. The self-organizing 6%Ni/CNM catalyst, where CNM is a carbon nanomaterial, resulted from carbon erosion of bulk Ni-Cr alloy (nichrome) in C2H4Cl2 vapors was also shown to be effective for catalytic chemical vapor deposition of CF2Cl2 with formation of bimodal carbon structures. It was demonstrated that interaction of nichrome with CF2Cl2/H2 reaction mixture at 600 °C leads to its rapid disintegration caused by carbon erosion to form disperse active Ni-particles catalyzing the growth of carbon filaments. The resulted filamentous carbon material is characterized with high textural parameters.

Bauman Y. , Mishakov I. , Korneev D. , Vedyagin A.
Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst
В сборнике Material Science and Engineering Technology VI : Selected papers presented at 6th International Conference on Material Science and Engineering Technology (ICMSET 2017), October 20-22, 2017, Seoul National University, Seoul, Korea. 2018. – C.122-126. – ISBN 978-3-0357-1213-1. DOI: 10.4028/www.scientific.net/MSF.917.122 Scopus РИНЦ OpenAlex

Поступила в редакцию:	31 окт. 2017 г.
Принята к публикации:	9 нояб. 2017 г.
Опубликована online:	27 мар. 2018 г.

Scopus:	2-s2.0-85045309985
РИНЦ:	35508980
OpenAlex:	W2790984454

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