Sciact
  • EN
  • RU

Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst Full article

Conference 6th International Conference on Material Science and Engineering Technology
20-22 Oct 2017 , Seoul
Source Material Science and Engineering Technology VI : Selected papers presented at 6th International Conference on Material Science and Engineering Technology (ICMSET 2017), October 20-22, 2017, Seoul National University, Seoul, Korea
Compilation, 2018. 368 c. ISBN 978-3-0357-1213-1.
Journal Materials Science Forum
ISSN: 0255-5476 , E-ISSN: 1662-9752
Output data Year: 2018, Volume: 917, Pages: 122-126 Pages count : 5 DOI: 10.4028/www.scientific.net/MSF.917.122
Tags 1,2-dichloroethane, Bulk alloys, Carbon erosion, Carbon fibers, Catalytic chemical vapor deposition, CFC-12, Halogenated hydrocarbons, Nichrome
Authors Bauman Yurii 1 , Mishakov Ilya 1,2 , Korneev Denis 3 , Vedyagin Aleksey 1,2
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
2 National Research Tomsk Polytechnic University, Tomsk, 634050, Russia
3 State Research Center of Virology and Biotechnology ‘‘Vector’’, 630559, Koltsovo, Russia

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2015-0004
2 The Ministry of Education and Science of the Russian Federation VIU-TOVPM-316/2017

Abstract: The way to produce the nanostructured carbon filaments via H2-assisted catalytic decomposition of CF2Cl2 over self-organizing Ni-based catalyst has been reported. The self-organizing 6%Ni/CNM catalyst, where CNM is a carbon nanomaterial, resulted from carbon erosion of bulk Ni-Cr alloy (nichrome) in C2H4Cl2 vapors was also shown to be effective for catalytic chemical vapor deposition of CF2Cl2 with formation of bimodal carbon structures. It was demonstrated that interaction of nichrome with CF2Cl2/H2 reaction mixture at 600 °C leads to its rapid disintegration caused by carbon erosion to form disperse active Ni-particles catalyzing the growth of carbon filaments. The resulted filamentous carbon material is characterized with high textural parameters.
Cite: Bauman Y. , Mishakov I. , Korneev D. , Vedyagin A.
Synthesis of Filamentous Carbon Material via Decomposition of CF2Cl2 over Self-Organizing Ni-Cr Catalyst
In compilation Material Science and Engineering Technology VI : Selected papers presented at 6th International Conference on Material Science and Engineering Technology (ICMSET 2017), October 20-22, 2017, Seoul National University, Seoul, Korea. 2018. – C.122-126. – ISBN 978-3-0357-1213-1. DOI: 10.4028/www.scientific.net/MSF.917.122 Scopus РИНЦ OpenAlex
Dates:
Submitted: Oct 31, 2017
Accepted: Nov 9, 2017
Published online: Mar 27, 2018
Identifiers:
Scopus: 2-s2.0-85045309985
Elibrary: 35508980
OpenAlex: W2790984454
Citing: Пока нет цитирований
Altmetrics: