Enhanced Enantiostability of BINOL Dimethyl Ether under Moderate Acidic Conditions | Sciact - CRIS-система Института катализа

Enhanced Enantiostability of BINOL Dimethyl Ether under Moderate Acidic Conditions Научная публикация

Журнал

Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X

Вых. Данные

Год: 2018, Том: 28, Номер: 1, Страницы: 27-28 Страниц : 2 DOI: 10.1016/j.mencom.2018.01.007

Ключевые слова

CATALYSIS; 1,1'-BI-2-NAPHTHOL

Авторы

Genaev Alexander M. ¹ , Salnikov George E. ^1,2 , Shernyukov Andrey V. ¹ , Zhu Zhongwei ² , Koltunov Konstantin Yu. ^2,3

Организации

1	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Информация о финансировании (1)

Российский фонд фундаментальных исследований

16-03-00357

Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.

Genaev A.M. , Salnikov G.E. , Shernyukov A.V. , Zhu Z. , Koltunov K.Y.
Enhanced Enantiostability of BINOL Dimethyl Ether under Moderate Acidic Conditions
Mendeleev Communications. 2018. V.28. N1. P.27-28. DOI: 10.1016/j.mencom.2018.01.007 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	28 мар. 2017 г.
Опубликована в печати:	1 янв. 2018 г.
Опубликована online:	6 февр. 2018 г.

Web of science:	WOS:000425204700007
Scopus:	2-s2.0-85041595732
РИНЦ:	35514582
Chemical Abstracts:	2018:253572
OpenAlex:	W2792904275

БД	Цитирований
Web of science	4
Scopus	4
РИНЦ	5
OpenAlex	5