Enhanced Enantiostability of BINOL Dimethyl Ether under Moderate Acidic Conditions | Sciact - CRIS-system of Boreskov Institute of Catalysis

Enhanced Enantiostability of BINOL Dimethyl Ether under Moderate Acidic Conditions Full article

Journal

Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X

Output data

Year: 2018, Volume: 28, Number: 1, Pages: 27-28 Pages count : 2 DOI: 10.1016/j.mencom.2018.01.007

Tags

CATALYSIS; 1,1'-BI-2-NAPHTHOL

Authors

Genaev Alexander M. ¹ , Salnikov George E. ^1,2 , Shernyukov Andrey V. ¹ , Zhu Zhongwei ² , Koltunov Konstantin Yu. ^2,3

Affiliations

1	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation
2	Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russian Federation
3	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

Funding (1)

Russian Foundation for Basic Research

16-03-00357

Compared with the parent 1,1’-bi-2-naphthol (BINOL), its dimethyl ether is highly resistant towards racemization under moderate acidic conditions. This finding confirms the hypothetical mechanism of BINOL atropisomerization including internal rotation around the C1 sp3 –C1' sp3 bond in its protonatedforms.

Genaev A.M. , Salnikov G.E. , Shernyukov A.V. , Zhu Z. , Koltunov K.Y.
Enhanced Enantiostability of BINOL Dimethyl Ether under Moderate Acidic Conditions
Mendeleev Communications. 2018. V.28. N1. P.27-28. DOI: 10.1016/j.mencom.2018.01.007 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Mar 28, 2017
Published print:	Jan 1, 2018
Published online:	Feb 6, 2018

Web of science:	WOS:000425204700007
Scopus:	2-s2.0-85041595732
Elibrary:	35514582
Chemical Abstracts:	2018:253572
OpenAlex:	W2792904275

DB	Citing
Web of science	4
Scopus	4
Elibrary	5
OpenAlex	5