Sciact
  • EN
  • RU

L-Serine Picrates Научная публикация

Журнал Journal of Molecular Structure
ISSN: 0022-2860
Вых. Данные Год: 2015, Том: 1100, Страницы: 255-263 Страниц : 9 DOI: 10.1016/j.molstruc.2015.07.051
Ключевые слова Crystal structure, Dimeric cationl, -serine picrate, Vibrational spectra
Авторы Zakharov B.A. 1,2 , Ghazaryan V.V. 3 , Boldyreva E.V. 1,2 , Petrosyan A.M. 3
Организации
1 Institute of Solid State Chemistry, Siberian Branch of the Russian Academy of Sciences, Kutateladze 18, Novosibirsk, Russian Federation
2 REC-008, Novosibirsk State University, Pirogova 2, Novosibirsk, Russian Federation
3 Institute of Applied Problems of Physics, NAS of Armenia, 25 Nersessyan Str., Yerevan, Armenia

Реферат: Two crystalline salts have been obtained from the system l-serine - picric acid - H<inf>2</inf>O: l-serinium picrate monohydrate (I) and tris(l-serine) bis(l-serinium) dipicrate trihydrate (II). The salt (I) crystallizes in monoclinic system (space group P2<inf>1</inf>, Z = 4). Asymmetric unit of (I) contains two formula units. Carboxyl groups of both l-serinium cations form hydrogen bonds with picrate anions with O···O distances: 2.595 (6) Å and 2.638 (5) Å. The salt (II) crystallizes in orthorhombic system (space group P2<inf>1</inf>2<inf>1</inf>2<inf>1</inf>, Z = 4). Asymmetric unit of (II) contains one formula unit. Carboxyl groups of both l-serinium cations form short O-H···O hydrogen bonds with two of three zwitterionic moieties, forming two dimeric (l-serine l-serinium) cations with O···O distances: 2.485 (3) Å and 2.487 (3) Å. The infrared and Raman spectra of obtained salts are recorded and discussed.
Библиографическая ссылка: Zakharov B.A. , Ghazaryan V.V. , Boldyreva E.V. , Petrosyan A.M.
L-Serine Picrates
Journal of Molecular Structure. 2015. V.1100. P.255-263. DOI: 10.1016/j.molstruc.2015.07.051 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 29 мар. 2015 г.
Принята к публикации: 24 июл. 2015 г.
Опубликована online: 28 июл. 2015 г.
Опубликована в печати: 1 нояб. 2015 г.
Идентификаторы БД:
Web of science: WOS:000365361600032
Scopus: 2-s2.0-84938863093
РИНЦ: 23997034
Chemical Abstracts: 2015:1312395
Chemical Abstracts (print): 163:368150
OpenAlex: W1431757052
Цитирование в БД:
БД Цитирований
Web of science 4
Scopus 4
OpenAlex 4
Альметрики: