L-Serine Picrates | Sciact - CRIS-system of Boreskov Institute of Catalysis

L-Serine Picrates Full article

Journal

Journal of Molecular Structure
ISSN: 0022-2860

Output data

Year: 2015, Volume: 1100, Pages: 255-263 Pages count : 9 DOI: 10.1016/j.molstruc.2015.07.051

Tags

Crystal structure, Dimeric cationl, -serine picrate, Vibrational spectra

Authors

Zakharov B.A. ^1,2 , Ghazaryan V.V. ³ , Boldyreva E.V. ^1,2 , Petrosyan A.M. ³

Affiliations

1	Institute of Solid State Chemistry, Siberian Branch of the Russian Academy of Sciences, Kutateladze 18, Novosibirsk, Russian Federation
2	REC-008, Novosibirsk State University, Pirogova 2, Novosibirsk, Russian Federation
3	Institute of Applied Problems of Physics, NAS of Armenia, 25 Nersessyan Str., Yerevan, Armenia

Two crystalline salts have been obtained from the system l-serine - picric acid - H<inf>2</inf>O: l-serinium picrate monohydrate (I) and tris(l-serine) bis(l-serinium) dipicrate trihydrate (II). The salt (I) crystallizes in monoclinic system (space group P2<inf>1</inf>, Z = 4). Asymmetric unit of (I) contains two formula units. Carboxyl groups of both l-serinium cations form hydrogen bonds with picrate anions with O···O distances: 2.595 (6) Å and 2.638 (5) Å. The salt (II) crystallizes in orthorhombic system (space group P2<inf>1</inf>2<inf>1</inf>2<inf>1</inf>, Z = 4). Asymmetric unit of (II) contains one formula unit. Carboxyl groups of both l-serinium cations form short O-H···O hydrogen bonds with two of three zwitterionic moieties, forming two dimeric (l-serine l-serinium) cations with O···O distances: 2.485 (3) Å and 2.487 (3) Å. The infrared and Raman spectra of obtained salts are recorded and discussed.

Zakharov B.A. , Ghazaryan V.V. , Boldyreva E.V. , Petrosyan A.M.
L-Serine Picrates
Journal of Molecular Structure. 2015. V.1100. P.255-263. DOI: 10.1016/j.molstruc.2015.07.051 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 29, 2015
Accepted:	Jul 24, 2015
Published online:	Jul 28, 2015
Published print:	Nov 1, 2015

Web of science:	WOS:000365361600032
Scopus:	2-s2.0-84938863093
Elibrary:	23997034
Chemical Abstracts:	2015:1312395
Chemical Abstracts (print):	163:368150
OpenAlex:	W1431757052

DB	Citing
Web of science	4
Scopus	4
OpenAlex	4