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Quadrupolar Metal NMR of Oxide Materials Including Catalysts Научная публикация

Сборник NMR of Quadrupolar Nuclei in Solid Materials
Монография, John Wiley & Sons, Inc.. 2012. 550 c. ISBN 9780470973981.
Вых. Данные Год: 2012, Страницы: 467-494 Страниц : 28 DOI: 10.1002/9780470034590.emrstm1224
Авторы Lapina O.B. 1 , Terskikh V.V. 2
Организации
1 Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk, Russia
2 Steacie Institute for Molecular Sciences, National Research Council Canada, Ottawa, Ontario, Canada

Реферат: In this work, we review the basic methodology and recent applications of quadrupolar metal solid-state NMR spectroscopy in oxide systems with emphasis on materials science and catalysis. Three typical quadrupolar metal nuclei, 51V, 93Nb, and 95Mo, are discussed in detail to illustrate the complex interplay between the quadrupolar and chemical shielding interactions in oxides. In the first part, a systematic overview is given of the metal coordination environments in oxides and their corresponding NMR parameters. The importance of quantum chemical calculations in correlating experimental NMR results with a molecular level oxide structure is highlighted. In the second part, we present examples of quadrupolar metal NMR in materials science, including paramagnetic oxide systems, layered materials, ferroelectrics, silicates, and glasses. The final section is dedicated to the latest applications of NMR in heterogeneous oxide catalysis.
Библиографическая ссылка: Lapina O.B. , Terskikh V.V.
Quadrupolar Metal NMR of Oxide Materials Including Catalysts
Глава монографии NMR of Quadrupolar Nuclei in Solid Materials. – John Wiley & Sons, Inc.., 2012. – Т.27. – C.467-494. – ISBN 9780470973981. DOI: 10.1002/9780470034590.emrstm1224 Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 15 дек. 2011 г.
Идентификаторы БД:
Scopus: 2-s2.0-85054348630
РИНЦ: 48671151
Chemical Abstracts: 2013:153790
Chemical Abstracts (print): 160:467910
OpenAlex: W1481049998
Цитирование в БД:
БД Цитирований
Scopus 11
РИНЦ 2
OpenAlex 10
Альметрики: