Quadrupolar Metal NMR of Oxide Materials Including Catalysts Full article
| Source | NMR of Quadrupolar Nuclei in Solid Materials Monography, John Wiley & Sons, Inc.. 2012. 550 c. ISBN 9780470973981. |
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| Output data | Year: 2012, Pages: 467-494 Pages count : 28 DOI: 10.1002/9780470034590.emrstm1224 | ||||
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Abstract:
In this work, we review the basic methodology and recent applications of quadrupolar metal solid-state NMR spectroscopy in oxide systems with emphasis on materials science and catalysis. Three typical quadrupolar metal nuclei, 51V, 93Nb, and 95Mo, are discussed in detail to illustrate the complex interplay between the quadrupolar and chemical shielding interactions in oxides. In the first part, a systematic overview is given of the metal coordination environments in oxides and their corresponding NMR parameters. The importance of quantum chemical calculations in correlating experimental NMR results with a molecular level oxide structure is highlighted. In the second part, we present examples of quadrupolar metal NMR in materials science, including paramagnetic oxide systems, layered materials, ferroelectrics, silicates, and glasses. The final section is dedicated to the latest applications of NMR in heterogeneous oxide catalysis.
Cite:
Lapina O.B.
, Terskikh V.V.
Quadrupolar Metal NMR of Oxide Materials Including Catalysts
Monography chapter NMR of Quadrupolar Nuclei in Solid Materials. – John Wiley & Sons, Inc.., 2012. – Т.27. – C.467-494. – ISBN 9780470973981. DOI: 10.1002/9780470034590.emrstm1224 Scopus РИНЦ ANCAN OpenAlex
Quadrupolar Metal NMR of Oxide Materials Including Catalysts
Monography chapter NMR of Quadrupolar Nuclei in Solid Materials. – John Wiley & Sons, Inc.., 2012. – Т.27. – C.467-494. – ISBN 9780470973981. DOI: 10.1002/9780470034590.emrstm1224 Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Dec 15, 2011 |
Identifiers:
| Scopus: | 2-s2.0-85054348630 |
| Elibrary: | 48671151 |
| Chemical Abstracts: | 2013:153790 |
| Chemical Abstracts (print): | 160:467910 |
| OpenAlex: | W1481049998 |