Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model | Sciact - CRIS-система Института катализа

Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model Научная публикация

Журнал

High Energy Chemistry
ISSN: 0018-1439

Вых. Данные

Год: 2018, Том: 52, Номер: 5, Страницы: 369-372 Страниц : 4 DOI: 10.1134/s0018143918050156

Ключевые слова

formose reaction, photoionization, anisometry, supercoiling, prebiological evolution

Авторы

Stovbun S. V. ¹ , Zanin A. M. ¹ , Mikhaleva M. G. ¹ , Skoblin A. A. ¹ , Tverdislov V. A. ² , Taran O. P. ^3,4 , Parmon V. N. ^3,5,6

Организации

1	Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991 Russia
2	Faculty of Physics, Moscow State University, Moscow, 119991 Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
4	Novosibirsk State Technical University, Novosibirsk, 630073 Russia
5	Novosibirsk State University, Novosibirsk, 630090 Russia
6	Tomsk State University, Tomsk, 634050 Russia

Информация о финансировании (1)

Федеральное агентство научных организаций России

0082-2014-0011 (АААА-А17-117111600093-8)

The structure formation in xerogels of aqueous solutions of products of the UV-initiated formose reaction has been studied in the context of the problem of the spontaneous formation of prebiological structures. Of the 11 variants of xerogels, only in the talopyranose xerogel show the presence of anisometric strings with distinct periodic (in particular, helical) structure, which form characteristic elements of biomimetic structures by interlacing. Under the conditions simulating the primitive Earth’s atmosphere (formaldehyde, water, UV), spontaneous formation of anisometric superhelical structures has been modeled and the type of the sugars forming these structures has been identified.

Stovbun S.V. , Zanin A.M. , Mikhaleva M.G. , Skoblin A.A. , Tverdislov V.A. , Taran O.P. , Parmon V.N.
Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model
High Energy Chemistry. 2018. V.52. N5. P.369-372. DOI: 10.1134/s0018143918050156 WOS Scopus РИНЦ CAPlus OpenAlex

Стовбун С.В. , Занин А.М. , Михалева М.Г. , Скоблин А.А. , Твердислов В.А. , Таран О.П. , Пармон В.Н.
Спонтанное структурообразование в продуктах УФ-инициированной формозной реакции в модели de novo
Химия высоких энергий. 2018. Т.52. №5. С.353-357. DOI: 10.1134/S0023119318050157 РИНЦ OpenAlex

Поступила в редакцию:	28 февр. 2018 г.
Опубликована в печати:	1 сент. 2018 г.
Опубликована online:	15 сент. 2018 г.

Web of science:	WOS:000444617700001
Scopus:	2-s2.0-85053398185
РИНЦ:	35726986
Chemical Abstracts:	2018:1730090
OpenAlex:	W2891410343

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