Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model | Sciact - CRIS-system of Boreskov Institute of Catalysis

Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model Full article

Journal

High Energy Chemistry
ISSN: 0018-1439

Output data

Year: 2018, Volume: 52, Number: 5, Pages: 369-372 Pages count : 4 DOI: 10.1134/s0018143918050156

Tags

formose reaction, photoionization, anisometry, supercoiling, prebiological evolution

Authors

Stovbun S. V. ¹ , Zanin A. M. ¹ , Mikhaleva M. G. ¹ , Skoblin A. A. ¹ , Tverdislov V. A. ² , Taran O. P. ^3,4 , Parmon V. N. ^3,5,6

Affiliations

1	Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991 Russia
2	Faculty of Physics, Moscow State University, Moscow, 119991 Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
4	Novosibirsk State Technical University, Novosibirsk, 630073 Russia
5	Novosibirsk State University, Novosibirsk, 630090 Russia
6	Tomsk State University, Tomsk, 634050 Russia

Funding (1)

Federal Agency for Scientific Organizations

0082-2014-0011 (АААА-А17-117111600093-8)

The structure formation in xerogels of aqueous solutions of products of the UV-initiated formose reaction has been studied in the context of the problem of the spontaneous formation of prebiological structures. Of the 11 variants of xerogels, only in the talopyranose xerogel show the presence of anisometric strings with distinct periodic (in particular, helical) structure, which form characteristic elements of biomimetic structures by interlacing. Under the conditions simulating the primitive Earth’s atmosphere (formaldehyde, water, UV), spontaneous formation of anisometric superhelical structures has been modeled and the type of the sugars forming these structures has been identified.

Stovbun S.V. , Zanin A.M. , Mikhaleva M.G. , Skoblin A.A. , Tverdislov V.A. , Taran O.P. , Parmon V.N.
Spontaneous Structure Formation in the Products of UV-Initiated Formose Reaction in De-Novo Model
High Energy Chemistry. 2018. V.52. N5. P.369-372. DOI: 10.1134/s0018143918050156 WOS Scopus РИНЦ AN OpenAlex

Стовбун С.В. , Занин А.М. , Михалева М.Г. , Скоблин А.А. , Твердислов В.А. , Таран О.П. , Пармон В.Н.
Спонтанное структурообразование в продуктах УФ-инициированной формозной реакции в модели de novo
Химия высоких энергий. 2018. Т.52. №5. С.353-357. DOI: 10.1134/S0023119318050157 РИНЦ OpenAlex

Submitted:	Feb 28, 2018
Published print:	Sep 1, 2018
Published online:	Sep 15, 2018

Web of science:	WOS:000444617700001
Scopus:	2-s2.0-85053398185
Elibrary:	35726986
Chemical Abstracts:	2018:1730090
OpenAlex:	W2891410343

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