Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement Обзор
| Журнал |
Chemistry - A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765 |
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| Вых. Данные | Год: 2019, Том: 25, Номер: 6, Страницы: 1420-1431 Страниц : 12 DOI: 10.1002/chem.201803515 | ||||||
| Ключевые слова | heterogeneous catalysis, homogeneous catalysis, imaging agents, NMR spectroscopy, supported catalysts | ||||||
| Авторы |
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| Организации |
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Информация о финансировании (3)
| 1 | Российский научный фонд | 17-73-20030 |
| 2 | Федеральное агентство научных организаций России | 0333-2018-0006 (II.1.13.1.) |
| 3 | Федеральное агентство научных организаций России | 0333-2017-0002 |
Реферат:
The catalysts with well defined single active centers are great importance and their utilization allows to bridging the gap between homogeneous and heterogeneous catalysis, and importantly to overcome the main selectivity problem of heterogeneous catalysis and the main separation challenge of homogeneous catalysis. Moreover, the use of single‐site catalysts allows to significantly enhance the NMR signal via pairwise hydrogen addition of two H atoms of parahydrogen molecule to an unsaturated substrates. This focus review covers the fundamentals of the synthesis of single‐site catalysts and shows the new aspects of their applications in both modern catalysis and parahydrogen based hyperpolarization field. The different novel aspects of single‐site catalysts formation and utilization along with the possibility of NMR signal enhancement observation are described.
Библиографическая ссылка:
Burueva D.B.
, Kovtunova L.M.
, Bukhtiyarov V.I.
, Kovtunov K.V.
, Koptyug I.V.
Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement
Chemistry - A European Journal. 2019. V.25. N6. P.1420-1431. DOI: 10.1002/chem.201803515 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement
Chemistry - A European Journal. 2019. V.25. N6. P.1420-1431. DOI: 10.1002/chem.201803515 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Даты:
| Поступила в редакцию: | 10 июл. 2018 г. |
| Опубликована online: | 10 авг. 2018 г. |
| Опубликована в печати: | 28 янв. 2019 г. |
Идентификаторы БД:
| Web of science: | WOS:000457477100006 |
| Scopus: | 2-s2.0-85056829703 |
| РИНЦ: | 38632798 |
| Chemical Abstracts: | 2018:2279774 |
| Chemical Abstracts (print): | 170:186893 |
| PMID (PubMed): | 30095187 |
| OpenAlex: | W2886459636 |