Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement Review
| Journal |
Chemistry - A European Journal
ISSN: 0947-6539 , E-ISSN: 1521-3765 |
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| Output data | Year: 2019, Volume: 25, Number: 6, Pages: 1420-1431 Pages count : 12 DOI: 10.1002/chem.201803515 | ||||||
| Tags | heterogeneous catalysis, homogeneous catalysis, imaging agents, NMR spectroscopy, supported catalysts | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Science Foundation | 17-73-20030 |
| 2 | Federal Agency for Scientific Organizations | 0333-2018-0006 (II.1.13.1.) |
| 3 | Federal Agency for Scientific Organizations | 0333-2017-0002 |
Abstract:
The catalysts with well defined single active centers are great importance and their utilization allows to bridging the gap between homogeneous and heterogeneous catalysis, and importantly to overcome the main selectivity problem of heterogeneous catalysis and the main separation challenge of homogeneous catalysis. Moreover, the use of single‐site catalysts allows to significantly enhance the NMR signal via pairwise hydrogen addition of two H atoms of parahydrogen molecule to an unsaturated substrates. This focus review covers the fundamentals of the synthesis of single‐site catalysts and shows the new aspects of their applications in both modern catalysis and parahydrogen based hyperpolarization field. The different novel aspects of single‐site catalysts formation and utilization along with the possibility of NMR signal enhancement observation are described.
Cite:
Burueva D.B.
, Kovtunova L.M.
, Bukhtiyarov V.I.
, Kovtunov K.V.
, Koptyug I.V.
Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement
Chemistry - A European Journal. 2019. V.25. N6. P.1420-1431. DOI: 10.1002/chem.201803515 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement
Chemistry - A European Journal. 2019. V.25. N6. P.1420-1431. DOI: 10.1002/chem.201803515 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
| Submitted: | Jul 10, 2018 |
| Published online: | Aug 10, 2018 |
| Published print: | Jan 28, 2019 |
Identifiers:
| Web of science: | WOS:000457477100006 |
| Scopus: | 2-s2.0-85056829703 |
| Elibrary: | 38632798 |
| Chemical Abstracts: | 2018:2279774 |
| Chemical Abstracts (print): | 170:186893 |
| PMID: | 30095187 |
| OpenAlex: | W2886459636 |