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XRD Study of the Local Structure and Phase Composition of Catalysts with Use of Synchrotron Radiation: Method of the Radial Distribution of Electron Density Научная публикация

Конференция XVII International Synchrotron Radiation Conference
15-20 июн. 2008 , Новосибирск
Журнал Nuclear Instruments and Methods in Physics Research Section A
ISSN: 0168-9002
Вых. Данные Год: 2009, Том: 603, Номер: 1-2, Страницы: 99-101 Страниц : 3 DOI: 10.1016/j.nima.2008.12.168
Ключевые слова Catalyst, Radial distribution function of electronic density, Synchrotron radiation, X-ray diffraction
Авторы Moroz E.M. 1 , Pakharukova V.P. 1 , Shmakov A.N. 1
Организации
1 Boreskov Institute of Catalysis, SB RAS, Pr. Lavrentieva, 5, 630090 Novosibirsk, Russia

Реферат: Some examples illustrating the use of the method based on the radial distribution function (RDF) of electronic density for investigation metal and oxide catalysts are reported. Using monoatomic unsupported metal catalysts with crystallite sizes D=40–450 Å, it was shown that the areas of coordination peaks in RDF directly define the absolute values of coordination numbers Z and depend on crystallite sizes. The investigation of the phase composition and local structure of supported metal catalysts revealed that the interaction between the active component and the support was responsible for the thermal stability of small supported metal particles. The local structure of ceria with different crystallite sizes was investigated.
Библиографическая ссылка: Moroz E.M. , Pakharukova V.P. , Shmakov A.N.
XRD Study of the Local Structure and Phase Composition of Catalysts with Use of Synchrotron Radiation: Method of the Radial Distribution of Electron Density
Nuclear Instruments and Methods in Physics Research Section A. 2009. V.603. N1-2. P.99-101. DOI: 10.1016/j.nima.2008.12.168 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 3 янв. 2009 г.
Опубликована в печати: 11 мая 2009 г.
Идентификаторы БД:
Web of science: WOS:000266760800030
Scopus: 2-s2.0-65449169125
РИНЦ: 13610230
Chemical Abstracts: 2009:569833
Chemical Abstracts (print): 152:108563
OpenAlex: W2018913512
Цитирование в БД:
БД Цитирований
Web of science 14
Scopus 14
РИНЦ 15
OpenAlex 12
Альметрики: