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XRD Study of the Local Structure and Phase Composition of Catalysts with Use of Synchrotron Radiation: Method of the Radial Distribution of Electron Density Full article

Conference XVII International Synchrotron Radiation Conference
15-20 Jun 2008 , Новосибирск
Journal Nuclear Instruments and Methods in Physics Research Section A
ISSN: 0168-9002
Output data Year: 2009, Volume: 603, Number: 1-2, Pages: 99-101 Pages count : 3 DOI: 10.1016/j.nima.2008.12.168
Tags Catalyst, Radial distribution function of electronic density, Synchrotron radiation, X-ray diffraction
Authors Moroz E.M. 1 , Pakharukova V.P. 1 , Shmakov A.N. 1
Affiliations
1 Boreskov Institute of Catalysis, SB RAS, Pr. Lavrentieva, 5, 630090 Novosibirsk, Russia

Abstract: Some examples illustrating the use of the method based on the radial distribution function (RDF) of electronic density for investigation metal and oxide catalysts are reported. Using monoatomic unsupported metal catalysts with crystallite sizes D=40–450 Å, it was shown that the areas of coordination peaks in RDF directly define the absolute values of coordination numbers Z and depend on crystallite sizes. The investigation of the phase composition and local structure of supported metal catalysts revealed that the interaction between the active component and the support was responsible for the thermal stability of small supported metal particles. The local structure of ceria with different crystallite sizes was investigated.
Cite: Moroz E.M. , Pakharukova V.P. , Shmakov A.N.
XRD Study of the Local Structure and Phase Composition of Catalysts with Use of Synchrotron Radiation: Method of the Radial Distribution of Electron Density
Nuclear Instruments and Methods in Physics Research Section A. 2009. V.603. N1-2. P.99-101. DOI: 10.1016/j.nima.2008.12.168 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Jan 3, 2009
Published print: May 11, 2009
Identifiers:
Web of science: WOS:000266760800030
Scopus: 2-s2.0-65449169125
Elibrary: 13610230
Chemical Abstracts: 2009:569833
Chemical Abstracts (print): 152:108563
OpenAlex: W2018913512
Citing:
DB Citing
Web of science 14
Scopus 14
Elibrary 15
OpenAlex 12
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