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The First Isolation of Lithium Perfluoroorganotrimethoxyborates Li [RFB(OMe)(3)] (R-F = C2F, CF2=CF and C6F5) - Three Samples of New Classes of Fluoroorganoboron Compounds Научная публикация

Журнал Main Group Metal Chemistry
ISSN: 0792-1241 , E-ISSN: 2191-0219
Вых. Данные Год: 2001, Том: 24, Номер: 12, Страницы: 845-846 Страниц : 2 DOI: 10.1515/MGMC.2001.24.12.845
Авторы Frohn Hermann-Josef 1 , Adonin Nicolay Yu. 2 , Bardin Vadim V. 2
Организации
1 Fachgebiet Anorganische Chemie, Gerhard-Mercator-Universität Duisburg, Lotharstr. 1, 2 D-47048 Duisburg, Germany
2 Ν. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, 630090 Novosibirsk, Russia

Реферат: The previously unknown classes of fluoroorganoboron compounds, lithium perfluoroorganotrimethoxyborates Li [R FB(OCH 3) 3] (R F = C 2F 5, CF 2=CF and C 6F 5), were prepared by the nucleophilic addition of R FLi to B(OCH 3) 3 in ether. The Li [R FB(OCH 3) 3] salts contain no ether coordinated at Li+ and are stable at room temperature towards elimination. In solution they show a differentiated behaviour of protodeborylation.
Библиографическая ссылка: Frohn H-J. , Adonin N.Y. , Bardin V.V.
The First Isolation of Lithium Perfluoroorganotrimethoxyborates Li [RFB(OMe)(3)] (R-F = C2F, CF2=CF and C6F5) - Three Samples of New Classes of Fluoroorganoboron Compounds
Main Group Metal Chemistry. 2001. V.24. N12. P.845-846. DOI: 10.1515/MGMC.2001.24.12.845 Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована в печати: 1 янв. 2001 г.
Опубликована online: 27 апр. 2011 г.
Идентификаторы БД:
Scopus: 2-s2.0-0000946442
РИНЦ: 41728862
Chemical Abstracts: 2002:29371
Chemical Abstracts (print): 136:294869
OpenAlex: W2142151230
Цитирование в БД:
БД Цитирований
Scopus 16
OpenAlex 11
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