Polyfluoroorganoboron-Oxygen Compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and Tri(aryl)boroxins Научная публикация
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Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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| Вых. Данные | Год: 2002, Том: 628, Номер: 13, Страницы: 2827-2833 Страниц : 7 DOI: 10.1002/1521-3749(200213)628:13<2827::aid-zaac2827>3.0.co;2-n | ||||
| Ключевые слова | Polyfluoroaryl(dihydroxy)boranes (Polyfluorophenylboronic acids); Tris(polyfluoroaryl)boroxins; Dehydration; NMR spectroscopy | ||||
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Реферат:
A general preparative procedure for polyfluorinated aryl(dihydroxy)boranes C6H5-nFnB(OH)(2) (n = 3 - 5) is described. Polyfluorinated aryl(dihydroxy)boranes are easily dehydrated to the corresponding tri(aryl)boroxins (C6H5-nFnBO)(3) by thermal or chemical treatment. The property of the acids C6H5-nFnB(OH)(2) to condensate depends on the number and on the position of the fluorine atoms in the aryl group. Examples of both classes of boron compounds were isolated as pure individuals and characterized by multinuclear NMR spectroscopy.
Библиографическая ссылка:
Frohn H.-J.
, Adonin N.Y.
, Bardin V.V.
, Starichenko V.F.
Polyfluoroorganoboron-Oxygen Compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and Tri(aryl)boroxins
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2827-2833. DOI: 10.1002/1521-3749(200213)628:13<2827::aid-zaac2827>3.0.co;2-n WOS Scopus РИНЦ OpenAlex
Polyfluoroorganoboron-Oxygen Compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and Tri(aryl)boroxins
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2827-2833. DOI: 10.1002/1521-3749(200213)628:13<2827::aid-zaac2827>3.0.co;2-n WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 11 февр. 2002 г. |
| Принята к публикации: | 30 мая 2002 г. |
| Опубликована online: | 19 нояб. 2002 г. |
Идентификаторы БД:
| Web of science: | WOS:000180534500006 |
| Scopus: | 2-s2.0-0036939933 |
| РИНЦ: | 13413441 |
| OpenAlex: | W1510803058 |