Polyfluoroorganoboron-Oxygen Compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and Tri(aryl)boroxins Full article
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Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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| Output data | Year: 2002, Volume: 628, Number: 13, Pages: 2827-2833 Pages count : 7 DOI: 10.1002/1521-3749(200213)628:13<2827::aid-zaac2827>3.0.co;2-n | ||||
| Tags | Polyfluoroaryl(dihydroxy)boranes (Polyfluorophenylboronic acids); Tris(polyfluoroaryl)boroxins; Dehydration; NMR spectroscopy | ||||
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Abstract:
A general preparative procedure for polyfluorinated aryl(dihydroxy)boranes C6H5-nFnB(OH)(2) (n = 3 - 5) is described. Polyfluorinated aryl(dihydroxy)boranes are easily dehydrated to the corresponding tri(aryl)boroxins (C6H5-nFnBO)(3) by thermal or chemical treatment. The property of the acids C6H5-nFnB(OH)(2) to condensate depends on the number and on the position of the fluorine atoms in the aryl group. Examples of both classes of boron compounds were isolated as pure individuals and characterized by multinuclear NMR spectroscopy.
Cite:
Frohn H.-J.
, Adonin N.Y.
, Bardin V.V.
, Starichenko V.F.
Polyfluoroorganoboron-Oxygen Compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and Tri(aryl)boroxins
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2827-2833. DOI: 10.1002/1521-3749(200213)628:13<2827::aid-zaac2827>3.0.co;2-n WOS Scopus РИНЦ OpenAlex
Polyfluoroorganoboron-Oxygen Compounds. 1 - Polyfluorinated aryl(dihydroxy)boranes and Tri(aryl)boroxins
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2827-2833. DOI: 10.1002/1521-3749(200213)628:13<2827::aid-zaac2827>3.0.co;2-n WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Feb 11, 2002 |
| Accepted: | May 30, 2002 |
| Published online: | Nov 19, 2002 |
Identifiers:
| Web of science: | WOS:000180534500006 |
| Scopus: | 2-s2.0-0036939933 |
| Elibrary: | 13413441 |
| OpenAlex: | W1510803058 |