Polyfluoroorganoboron-Oxygen Compounds. 2 [1] - Base-Catalysed Hydrodeboration of Polyfluorophenyl(dihydroxy)boranes Научная публикация
| Журнал |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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| Вых. Данные | Год: 2002, Том: 628, Номер: 13, Страницы: 2834-2838 Страниц : 5 DOI: 10.1002/1521-3749(200213)628:13<2834::aid-zaac2834>3.0.co;2-2 | ||||
| Ключевые слова | Polyfluorophenyl(dihydroxy)boranes (Polyfluorophenylboronic acids); Hydrodeboration; NMR spectroscopy | ||||
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Реферат:
Polyfluorinated phenyl(dihydroxy)boranes C6H5-nFnB(OH)(2) (n = 3 - 5) underwent hydrodeboration (formal replacement of the (dihydroxy)boryl group by hydrogen) in the presence of bases (MeOH, 33% H2O-MeOH, KOH (1 equiv.)/33% H2O-MeOH, pyridine and 9% D2O-pyridine) and formed the fluoroaromatic compounds ArH or ArD, respectively. The rate of reaction depends on the number of fluorine atoms in the phenyl group and on the position of the fluorine atoms, relative to the B(OH)(2) substituent.
Библиографическая ссылка:
Frohn H.-J.
, Adonin N.Y.
, Bardin V.V.
, Starichenko V.F.
Polyfluoroorganoboron-Oxygen Compounds. 2 [1] - Base-Catalysed Hydrodeboration of Polyfluorophenyl(dihydroxy)boranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2834-2838. DOI: 10.1002/1521-3749(200213)628:13<2834::aid-zaac2834>3.0.co;2-2 WOS Scopus РИНЦ OpenAlex
Polyfluoroorganoboron-Oxygen Compounds. 2 [1] - Base-Catalysed Hydrodeboration of Polyfluorophenyl(dihydroxy)boranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2834-2838. DOI: 10.1002/1521-3749(200213)628:13<2834::aid-zaac2834>3.0.co;2-2 WOS Scopus РИНЦ OpenAlex
Даты:
| Поступила в редакцию: | 11 февр. 2002 г. |
| Принята к публикации: | 30 мая 2002 г. |
| Опубликована online: | 19 нояб. 2002 г. |
Идентификаторы БД:
| Web of science: | WOS:000180534500007 |
| Scopus: | 2-s2.0-0036943387 |
| РИНЦ: | 13392789 |
| OpenAlex: | W1602948241 |