Polyfluoroorganoboron-Oxygen Compounds. 2 [1] - Base-Catalysed Hydrodeboration of Polyfluorophenyl(dihydroxy)boranes Full article
| Journal |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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| Output data | Year: 2002, Volume: 628, Number: 13, Pages: 2834-2838 Pages count : 5 DOI: 10.1002/1521-3749(200213)628:13<2834::aid-zaac2834>3.0.co;2-2 | ||||
| Tags | Polyfluorophenyl(dihydroxy)boranes (Polyfluorophenylboronic acids); Hydrodeboration; NMR spectroscopy | ||||
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Abstract:
Polyfluorinated phenyl(dihydroxy)boranes C6H5-nFnB(OH)(2) (n = 3 - 5) underwent hydrodeboration (formal replacement of the (dihydroxy)boryl group by hydrogen) in the presence of bases (MeOH, 33% H2O-MeOH, KOH (1 equiv.)/33% H2O-MeOH, pyridine and 9% D2O-pyridine) and formed the fluoroaromatic compounds ArH or ArD, respectively. The rate of reaction depends on the number of fluorine atoms in the phenyl group and on the position of the fluorine atoms, relative to the B(OH)(2) substituent.
Cite:
Frohn H.-J.
, Adonin N.Y.
, Bardin V.V.
, Starichenko V.F.
Polyfluoroorganoboron-Oxygen Compounds. 2 [1] - Base-Catalysed Hydrodeboration of Polyfluorophenyl(dihydroxy)boranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2834-2838. DOI: 10.1002/1521-3749(200213)628:13<2834::aid-zaac2834>3.0.co;2-2 WOS Scopus РИНЦ OpenAlex
Polyfluoroorganoboron-Oxygen Compounds. 2 [1] - Base-Catalysed Hydrodeboration of Polyfluorophenyl(dihydroxy)boranes
Zeitschrift fur Anorganische und Allgemeine Chemie. 2002. V.628. N13. P.2834-2838. DOI: 10.1002/1521-3749(200213)628:13<2834::aid-zaac2834>3.0.co;2-2 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Feb 11, 2002 |
| Accepted: | May 30, 2002 |
| Published online: | Nov 19, 2002 |
Identifiers:
| Web of science: | WOS:000180534500007 |
| Scopus: | 2-s2.0-0036943387 |
| Elibrary: | 13392789 |
| OpenAlex: | W1602948241 |