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A Large Anisotropic Plasticity of L-Leucinium Hydrogen Maleate Preserved at Cryogenic Temperatures Full article

Journal Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
ISSN: 2052-5192 , E-ISSN: 2052-5206
Output data Year: 2019, Volume: 75 B, Number: 2, Pages: 143-151 Pages count : 9 DOI: 10.1107/s2052520619000441
Tags plastic crystals; low temperature; hydrogen bonds; intermolecular interactions
Authors Arkhipov S.G. 1,2,3 , Losev E.A. 1,2,3 , Nguyen T.T. 1 , Rychkov D.A. 1,2 , Boldyreva E.V. 1,3
Affiliations
1 Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russian Federation
2 Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, 630128, Russian Federation
3 Boreskov Institute of Catalysis SB RAS, Lavrentiev Ave. 5, Novosibirsk, 630090, Russian Federation

Funding (4)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2019-0003
2 Russian Foundation for Basic Research 16-33-60089 (АААА-А16-116021550280-1)
3 Russian Foundation for Basic Research 18-43-543004 (АААА-А18-118061890006-6)
4 The Ministry of Education and Science of the Russian Federation Проект 5-100

Abstract: L-Leucinium hydrogen maleate crystals are very plastic at ambient conditions. Here it is shown that this plasticity is preserved at least down to 77 K. The structural changes in the temperature range 293–100 K were followed in order to rationalize the large anisotropic plasticity in this compound. To the best of our knowledge, this is the first reported example of an organic compound remaining so plastic at cryogenic conditions.
Cite: Arkhipov S.G. , Losev E.A. , Nguyen T.T. , Rychkov D.A. , Boldyreva E.V.
A Large Anisotropic Plasticity of L-Leucinium Hydrogen Maleate Preserved at Cryogenic Temperatures
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials. 2019. V.75 B. N2. P.143-151. DOI: 10.1107/s2052520619000441 WOS Scopus РИНЦ OpenAlex AN
Dates:
Submitted: Dec 6, 2018
Accepted: Jan 8, 2019
Published online: Mar 13, 2019
Published print: Apr 1, 2019
Identifiers:
≡ Web of science: WOS:000463912400005
≡ Scopus: 2-s2.0-85063033352
≡ Elibrary: 45554420
≡ OpenAlex: W2921647223
≡ Chemical Abstracts: 2019:733580
Citing:
≡ Scopus 17 Сбор данных от 15.02.2026
≡ Web of science 17 Сбор данных от 13.02.2026
≡ Elibrary 17 Сбор данных от 15.02.2026
≡ OpenAlex 18 Сбор данных от 15.02.2026
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