Methane Peroxide Oxidation over Fe-Containing MFI: Effect of the Catalyst Texture and Surface Properties Тезисы доклада
| Конференция |
The 8th Tokyo Conference on Advanced Catalytic Science and Technology 05-10 авг. 2018 , Токио |
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| Сборник | The 8th Tokyo Conference on Advanced Catalytic Science and Technology Сборник, 2018. |
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| Вых. Данные | Год: 2018, Номер статьи : P1246, Страниц : 2 | ||||
| Ключевые слова | Fe-ZSM-5, Fe-silicalite, Formic acid, Methanol | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Российский научный фонд | 17-73-30032 |
Реферат:
The selectivity of Fe-MFI catalysts to partial peroxide oxidation of methane to methanol and
formic acid was studied depending on their topology (Nanocrystals, Microcrystals, and bulk Commercial)
and activation with oxalic acid. The increase in TOF and selectivity to formic acid, as well as a sharp
decrease in the selectivity to CO2 over all the activated catalysts were accounted for by an increase in the
total acidity of the catalysts and the number of oligomeric Fe oxo-clusters. Different pathways to the
formation of methanol/CO2 (via free radical mechanism) and formic acid (via heterogeneous route) over FeMFI catalysts were suggested
Библиографическая ссылка:
Taran O.
, Boltenkov V.
, Yashnik S.
, Parkhomchuk E.
, Sashkina K.
, Babushkin D.
, Parmon V.
Methane Peroxide Oxidation over Fe-Containing MFI: Effect of the Catalyst Texture and Surface Properties
В сборнике The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
Methane Peroxide Oxidation over Fe-Containing MFI: Effect of the Catalyst Texture and Surface Properties
В сборнике The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
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