Methane Peroxide Oxidation over Fe-Containing MFI: Effect of the Catalyst Texture and Surface Properties Conference Abstracts
| Conference |
The 8th Tokyo Conference on Advanced Catalytic Science and Technology 05-10 Aug 2018 , Токио |
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| Source | The 8th Tokyo Conference on Advanced Catalytic Science and Technology Compilation, 2018. |
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| Output data | Year: 2018, Article number : P1246, Pages count : 2 | ||||
| Tags | Fe-ZSM-5, Fe-silicalite, Formic acid, Methanol | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 17-73-30032 |
Abstract:
The selectivity of Fe-MFI catalysts to partial peroxide oxidation of methane to methanol and
formic acid was studied depending on their topology (Nanocrystals, Microcrystals, and bulk Commercial)
and activation with oxalic acid. The increase in TOF and selectivity to formic acid, as well as a sharp
decrease in the selectivity to CO2 over all the activated catalysts were accounted for by an increase in the
total acidity of the catalysts and the number of oligomeric Fe oxo-clusters. Different pathways to the
formation of methanol/CO2 (via free radical mechanism) and formic acid (via heterogeneous route) over FeMFI catalysts were suggested
Cite:
Taran O.
, Boltenkov V.
, Yashnik S.
, Parkhomchuk E.
, Sashkina K.
, Babushkin D.
, Parmon V.
Methane Peroxide Oxidation over Fe-Containing MFI: Effect of the Catalyst Texture and Surface Properties
In compilation The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
Methane Peroxide Oxidation over Fe-Containing MFI: Effect of the Catalyst Texture and Surface Properties
In compilation The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
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