Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols | Sciact - CRIS-система Института катализа

Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols Обзор

Журнал

Mini-Reviews in Organic Chemistry
ISSN: 1570-193X , E-ISSN: 1875-6298

Вых. Данные

Год: 2019, Том: 16, Номер: 4, Страницы: 392-398 Страниц : 7 DOI: 10.2174/1570193x15666180418153713

Ключевые слова

Asymmetric synthesis, 2-naphthol, BINOL, aerobic oxidative coupling, transition metals, mechanism

Авторы

Tkachenko Nikolay V. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Lavrentieva 5, 630090, Novosibirsk, Russia

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0005
2	Российский фонд фундаментальных исследований	17-03-00991

Optically pure 1,1′-bi-2-naphthol (BINOL) and its derivatives are among the most widely used chiral ligands and auxiliaries for asymmetric synthesis. These molecules also occur as scaffolds for various biologically active compounds. Direct oxidative coupling of 2-naphthols in the presence of chiral catalysts provides a powerful strategy for the synthesis of optically pure 1,1′-bi-2-naphthols (BINOLS). In 1978, Wynberg with co-workers discovered that a copper salt with chiral auxiliary mediates the oxidative coupling of 2-naphthols, which can be taken as the starting point for further progress in this area. Over the last decades, a number of efficient and stereoselective catalyst systems have been developed. This mini-review surveys the aerobic asymmetric oxidative coupling of 2-naphthols catalyzed by transition metal complexes reported since 1995.

Tkachenko N.V. , Bryliakov K.P.
Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols
Mini-Reviews in Organic Chemistry. 2019. V.16. N4. P.392-398. DOI: 10.2174/1570193x15666180418153713 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	23 февр. 2018 г.
Принята к публикации:	9 апр. 2018 г.
Опубликована в печати:	15 янв. 2019 г.

Web of science:	WOS:000461717500009
Scopus:	2-s2.0-85063740892
РИНЦ:	38722800
Chemical Abstracts:	2019:667125
OpenAlex:	W2801149897

БД	Цитирований
Web of science	18
Scopus	20
РИНЦ	14
OpenAlex	19