Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols Review
| Journal |
Mini-Reviews in Organic Chemistry
ISSN: 1570-193X , E-ISSN: 1875-6298 |
||||
|---|---|---|---|---|---|
| Output data | Year: 2019, Volume: 16, Number: 4, Pages: 392-398 Pages count : 7 DOI: 10.2174/1570193x15666180418153713 | ||||
| Tags | Asymmetric synthesis, 2-naphthol, BINOL, aerobic oxidative coupling, transition metals, mechanism | ||||
| Authors |
|
||||
| Affiliations |
|
Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0005 |
| 2 | Russian Foundation for Basic Research | 17-03-00991 |
Abstract:
Optically pure 1,1′-bi-2-naphthol (BINOL) and its derivatives are among the most widely used chiral ligands and auxiliaries for asymmetric synthesis. These molecules also occur as scaffolds for various biologically active compounds. Direct oxidative coupling of 2-naphthols in the presence of chiral catalysts provides a powerful strategy for the synthesis of optically pure 1,1′-bi-2-naphthols (BINOLS). In 1978, Wynberg with co-workers discovered that a copper salt with chiral auxiliary mediates the oxidative coupling of 2-naphthols, which can be taken as the starting point for further progress in this area. Over the last decades, a number of efficient and stereoselective catalyst systems have been developed. This mini-review surveys the aerobic asymmetric oxidative coupling of 2-naphthols catalyzed by transition metal complexes reported since 1995.
Cite:
Tkachenko N.V.
, Bryliakov K.P.
Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols
Mini-Reviews in Organic Chemistry. 2019. V.16. N4. P.392-398. DOI: 10.2174/1570193x15666180418153713 WOS Scopus РИНЦ AN OpenAlex
Transition Metal Catalyzed Aerobic Asymmetric Coupling of 2-Naphthols
Mini-Reviews in Organic Chemistry. 2019. V.16. N4. P.392-398. DOI: 10.2174/1570193x15666180418153713 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Feb 23, 2018 |
| Accepted: | Apr 9, 2018 |
| Published print: | Jan 15, 2019 |
Identifiers:
| Web of science: | WOS:000461717500009 |
| Scopus: | 2-s2.0-85063740892 |
| Elibrary: | 38722800 |
| Chemical Abstracts: | 2019:667125 |
| OpenAlex: | W2801149897 |