Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups | Sciact - CRIS-система Института катализа

Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups Тезисы доклада

Конференция

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 авг. 2017 , Florence

Сборник

13th European Congress on Catalysis
Сборник, 2017.

Вых. Данные

Год: 2017, Номер статьи : SS17.6, Страниц : 2

Авторы

Zima A. ^1,2 , Lyakin O.Y. ^1,2 , Bryliakov K.P. ^1,2 , Talsi E.P. ^1,2

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, 630090, Russia

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0005
2	Российский фонд фундаментальных исследований	17-03-00991

The active species of the catalyst systems based on biomimetic iron complexes with aminopyridine ligands and various oxidants were studied. Depending on the nature of aminopyridine ligand, the catalyst systems exhibit EPR signals of three types of iron-oxygen intermediates I – III that are able to directly oxygenate C=C and C–H groups at low temperatures. Catalyst systems based on considered iron complexes were compared towards enantioselective epoxidation of chalcone, chemoselective hydroxylation of cyclohexane and regioselective hydroxylation of adamantane

Zima A. , Lyakin O.Y. , Bryliakov K.P. , Talsi E.P.
Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups
В сборнике 13th European Congress on Catalysis. 2017. – C.205-206.

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