Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups | Sciact - CRIS-system of Boreskov Institute of Catalysis

Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups Conference Abstracts

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Source

13th European Congress on Catalysis
Compilation, 2017.

Output data

Year: 2017, Article number : SS17.6, Pages count : 2

Authors

Zima A. ^1,2 , Lyakin O.Y. ^1,2 , Bryliakov K.P. ^1,2 , Talsi E.P. ^1,2

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, 630090, Russia

Funding (2)

1	Federal Agency for Scientific Organizations	0303-2016-0005
2	Russian Foundation for Basic Research	17-03-00991

The active species of the catalyst systems based on biomimetic iron complexes with aminopyridine ligands and various oxidants were studied. Depending on the nature of aminopyridine ligand, the catalyst systems exhibit EPR signals of three types of iron-oxygen intermediates I – III that are able to directly oxygenate C=C and C–H groups at low temperatures. Catalyst systems based on considered iron complexes were compared towards enantioselective epoxidation of chalcone, chemoselective hydroxylation of cyclohexane and regioselective hydroxylation of adamantane

Zima A. , Lyakin O.Y. , Bryliakov K.P. , Talsi E.P.
Oxoiron(V) Intermediates that Oxygenate C=C and C-H Groups
In compilation 13th European Congress on Catalysis. 2017. – C.205-206.

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