Catalytic Asymmetric C–H Oxidation with H2O2 and O2 Научная публикация
| Сборник | Frontiers of Green Catalytic Selective Oxidations Монография, Springer. Singapore.2019. 295 c. ISBN 9789813297500. WOS |
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| Вых. Данные | Год: 2019, Номер: Ch. 11, Страницы: 277-295 Страниц : 19 DOI: 10.1007/978-981-32-9751-7_11 | ||||
| Ключевые слова | Asymmetric oxidation - C–H oxidation - Dioxygen - Homogeneous catalysis - Hydrogen peroxide - Mechanism | ||||
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Информация о финансировании (2)
| 1 | Российский фонд фундаментальных исследований | 16-29-10666 |
| 2 | Российский фонд фундаментальных исследований | 18-33-20078 |
Реферат:
This chapter surveys the existing catalyst systems, either organocatalytic or metal-based, for the chemo- and stereoselective oxidation of C–H groups with the environmentally benign oxidants H2O2 and O2, reported in the last 30 years. Both the approaches relying on “classical” asymmetric oxidation and oxidative desymmetrization of complex substrates are considered, with focus on the catalytic properties of the catalysts, such as chemo- and stereoselectivity, activity, efficiency, and substrate scope. Currently available data on the nature of the catalytically active sites, the mechanisms of oxidant activation and C–H activation, and of oxygen transfer, are presented.
Библиографическая ссылка:
Bryliakov K.P.
Catalytic Asymmetric C–H Oxidation with H2O2 and O2
Глава монографии Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.277-295. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_11 WOS OpenAlex
Catalytic Asymmetric C–H Oxidation with H2O2 and O2
Глава монографии Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.277-295. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_11 WOS OpenAlex
Даты:
| Опубликована online: | 2 окт. 2019 г. |
Идентификаторы БД:
| Web of science: | WOS:000620352300012 |
| OpenAlex: | W2978613991 |