Catalytic Asymmetric C–H Oxidation with H2O2 and O2 Full article
| Source | Frontiers of Green Catalytic Selective Oxidations Monography, Springer. Singapore.2019. 295 c. ISBN 9789813297500. WOS |
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| Output data | Year: 2019, Number: Ch. 11, Pages: 277-295 Pages count : 19 DOI: 10.1007/978-981-32-9751-7_11 | ||||
| Tags | Asymmetric oxidation - C–H oxidation - Dioxygen - Homogeneous catalysis - Hydrogen peroxide - Mechanism | ||||
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Funding (2)
| 1 | Russian Foundation for Basic Research | 16-29-10666 |
| 2 | Russian Foundation for Basic Research | 18-33-20078 |
Abstract:
This chapter surveys the existing catalyst systems, either organocatalytic or metal-based, for the chemo- and stereoselective oxidation of C–H groups with the environmentally benign oxidants H2O2 and O2, reported in the last 30 years. Both the approaches relying on “classical” asymmetric oxidation and oxidative desymmetrization of complex substrates are considered, with focus on the catalytic properties of the catalysts, such as chemo- and stereoselectivity, activity, efficiency, and substrate scope. Currently available data on the nature of the catalytically active sites, the mechanisms of oxidant activation and C–H activation, and of oxygen transfer, are presented.
Cite:
Bryliakov K.P.
Catalytic Asymmetric C–H Oxidation with H2O2 and O2
Monography chapter Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.277-295. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_11 WOS OpenAlex
Catalytic Asymmetric C–H Oxidation with H2O2 and O2
Monography chapter Frontiers of Green Catalytic Selective Oxidations. – Springer., 2019. – C.277-295. – ISBN 9789813297500. DOI: 10.1007/978-981-32-9751-7_11 WOS OpenAlex
Dates:
| Published online: | Oct 2, 2019 |
Identifiers:
| Web of science: | WOS:000620352300012 |
| OpenAlex: | W2978613991 |