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Active Sites and Mechanisms of Bioinspired Oxidation with H2O2, Catalyzed by Non-Heme Fe and Related Mn Complexes Обзор

Журнал Coordination Chemistry Reviews
ISSN: 0010-8545 , E-ISSN: 1873-3840
Вых. Данные Год: 2014, Том: 276, Страницы: 73-96 Страниц : 24 DOI: 10.1016/j.ccr.2014.06.009
Ключевые слова Active site, Bioinspired, Iron, Manganese, Mechanism, Oxidation
Авторы Bryliakov Konstantin P. 1,2 , Talsi Evgenii P. 1,2
Организации
1 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation
2 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation

Информация о финансировании (1)

1 Российский научный фонд 14-13-00158

Реферат: In the last two decades, considerable efforts were invested in the search for synthetic iron and manganese catalysts with nonporphyrinic ligands, mimicking metalloenzymes in the oxygenation at Csingle bondH and Cdouble bond; length as m-dashC bonds of organic molecules. In many cases, the detailed knowledge of intimate reaction mechanisms and of the nature of active sites was critical for the rational design of biomimetic catalysts with predictable reactivities. This review discusses the up-to-date mechanistic landscape of non-heme iron and manganese catalyzed oxidations of olefinic groups and aliphatic Csingle bondH groups with H2O2.
Библиографическая ссылка: Bryliakov K.P. , Talsi E.P.
Active Sites and Mechanisms of Bioinspired Oxidation with H2O2, Catalyzed by Non-Heme Fe and Related Mn Complexes
Coordination Chemistry Reviews. 2014. V.276. P.73-96. DOI: 10.1016/j.ccr.2014.06.009 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 28 апр. 2014 г.
Принята к публикации: 13 июн. 2014 г.
Опубликована online: 21 июн. 2014 г.
Опубликована в печати: 15 сент. 2014 г.
Идентификаторы БД:
Web of science: WOS:000340321000004
Scopus: 2-s2.0-84903690922
РИНЦ: 24063865
Chemical Abstracts: 2014:1200011
OpenAlex: W2056866121
Цитирование в БД:
БД Цитирований
Web of science 201
Scopus 211
РИНЦ 206
OpenAlex 223
Альметрики: