Active Sites and Mechanisms of Bioinspired Oxidation with H2O2, Catalyzed by Non-Heme Fe and Related Mn Complexes Review
| Journal |
Coordination Chemistry Reviews
ISSN: 0010-8545 , E-ISSN: 1873-3840 |
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| Output data | Year: 2014, Volume: 276, Pages: 73-96 Pages count : 24 DOI: 10.1016/j.ccr.2014.06.009 | ||||
| Tags | Active site, Bioinspired, Iron, Manganese, Mechanism, Oxidation | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-13-00158 |
Abstract:
In the last two decades, considerable efforts were invested in the search for synthetic iron and manganese catalysts with nonporphyrinic ligands, mimicking metalloenzymes in the oxygenation at Csingle bondH and Cdouble bond; length as m-dashC bonds of organic molecules. In many cases, the detailed knowledge of intimate reaction mechanisms and of the nature of active sites was critical for the rational design of biomimetic catalysts with predictable reactivities. This review discusses the up-to-date mechanistic landscape of non-heme iron and manganese catalyzed oxidations of olefinic groups and aliphatic Csingle bondH groups with H2O2.
Cite:
Bryliakov K.P.
, Talsi E.P.
Active Sites and Mechanisms of Bioinspired Oxidation with H2O2, Catalyzed by Non-Heme Fe and Related Mn Complexes
Coordination Chemistry Reviews. 2014. V.276. P.73-96. DOI: 10.1016/j.ccr.2014.06.009 WOS Scopus РИНЦ AN OpenAlex
Active Sites and Mechanisms of Bioinspired Oxidation with H2O2, Catalyzed by Non-Heme Fe and Related Mn Complexes
Coordination Chemistry Reviews. 2014. V.276. P.73-96. DOI: 10.1016/j.ccr.2014.06.009 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Apr 28, 2014 |
| Accepted: | Jun 13, 2014 |
| Published online: | Jun 21, 2014 |
| Published print: | Sep 15, 2014 |
Identifiers:
| Web of science: | WOS:000340321000004 |
| Scopus: | 2-s2.0-84903690922 |
| Elibrary: | 24063865 |
| Chemical Abstracts: | 2014:1200011 |
| OpenAlex: | W2056866121 |