Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO2/γ-Al2O3 Catalyst | Sciact - CRIS-система Института катализа

Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO2/γ-Al2O3 Catalyst Научная публикация

Журнал

Energies
ISSN: 1996-1073

Вых. Данные

Год: 2020, Том: 13, Номер: 14, Номер статьи : 3684, Страниц : 10 DOI: 10.3390/en13143684

Ключевые слова

dimethoxymethane; hydrogen production; CuO-CeO2/γ-Al2O3; oxidative steam reforming; partial oxidation; copper catalyst; fuel cell

Авторы

Badmaev Sukhe ^1,2 , Sobyanin Vladimir ¹

Организации

1	Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
2	Department of Natural Sciences, Novosibirsk State University, Pirogova St. 2, 630090 Novosibirsk, Russia

Информация о финансировании (1)

Федеральное агентство научных организаций России

0303-2016-0011

The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h−1 gcat−1 at 280 °C, GHSV (gas hourly space velocity) = 15,000 h−1 and DMM:O2:H2O:N2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.

Badmaev S. , Sobyanin V.
Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO2/γ-Al2O3 Catalyst

Energies. 2020. V.13. N14. 3684 :1-10. DOI: 10.3390/en13143684 WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	25 июн. 2020 г.
Принята к публикации:	14 июл. 2020 г.
Опубликована в печати:	17 июл. 2020 г.
Опубликована online:	17 июл. 2020 г.

Web of science:	WOS:000556515900001
Scopus:	2-s2.0-85089822164
РИНЦ:	45364135
Chemical Abstracts:	2020:2041137
OpenAlex:	W3042446200

БД	Цитирований
Scopus	1