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Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO2/γ-Al2O3 Catalyst Full article

Journal Energies
ISSN: 1996-1073
Output data Year: 2020, Volume: 13, Number: 14, Article number : 3684, Pages count : 10 DOI: 10.3390/en13143684
Tags dimethoxymethane; hydrogen production; CuO-CeO2/γ-Al2O3; oxidative steam reforming; partial oxidation; copper catalyst; fuel cell
Authors Badmaev Sukhe 1,2 , Sobyanin Vladimir 1
Affiliations
1 Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
2 Department of Natural Sciences, Novosibirsk State University, Pirogova St. 2, 630090 Novosibirsk, Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0011

Abstract: The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h−1 gcat−1 at 280 °C, GHSV (gas hourly space velocity) = 15,000 h−1 and DMM:O2:H2O:N2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.
Cite: Badmaev S. , Sobyanin V.
Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO2/γ-Al2O3 Catalyst
Energies. 2020. V.13. N14. 3684 :1-10. DOI: 10.3390/en13143684 WOS Scopus РИНЦ AN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Jun 25, 2020
Accepted: Jul 14, 2020
Published print: Jul 17, 2020
Published online: Jul 17, 2020
Identifiers:
Web of science: WOS:000556515900001
Scopus: 2-s2.0-85089822164
Elibrary: 45364135
Chemical Abstracts: 2020:2041137
OpenAlex: W3042446200
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