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Synthesis Gas Production from Bio-Oil: Steam Reforming of Ethanol as a Model Compound Научная публикация

Журнал RSC Advances
ISSN: 2046-2069
Вых. Данные Год: 2014, Том: 4, Номер: 72, Страницы: 37964-37972 Страниц : 9 DOI: 10.1039/C4RA05948D
Ключевые слова Aluminum; Ethanol; Ethylene; Steam reforming; Zirconium
Авторы Pavlova S. 1 , Yaseneva P. 2 , Sadykov V. 1 , Rogov V. 1 , Tikhov S. 1 , Bespalko Yu. 1 , Beloshapkin S. 3 , Ross J. 4
Организации
1 Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, 630090, Novosibirsk, Russiab
2 University of Cambridge, UK
3 Materials & Surface Science Institute, Limerick, Ireland
4 University of Limerick, Limerick, Ireland

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 12-03-93115
2 Сибирское отделение Российской академии наук 8

Реферат: Using original hydrothermal technology honeycomb corundum monoliths with a peculiar porous structure and high water-adsorbing capacity facilitating procedures of active component loading have been produced. The detailed study of ethanol steam reforming over Ru/Ce0.5Zr0.5O2(CZ), Ru/Ce0.4Zr0.4Sm0.2O2–(δ + γ)Al2O3 (granulated) and Ru/Ce0.4Zr0.4Sm0.2O2/α-Al2O3 (monolithic) has been performed. It has been revealed that the main route of the reaction over Ru/CZ is ethanol dehydrogenation while ethanol dehydration into ethylene mainly occurs over Ru/CZS–Al2O3. Variation of the H2O–EtOH ratio, contact time and temperature allows hydrogen and CO yield to be governed. The monolithic catalyst has shown a high performance and stability at short contact time (0.1–0.4 s) and low water concentration (H2O–EtOH [similar] 1–3).
Библиографическая ссылка: Pavlova S. , Yaseneva P. , Sadykov V. , Rogov V. , Tikhov S. , Bespalko Y. , Beloshapkin S. , Ross J.
Synthesis Gas Production from Bio-Oil: Steam Reforming of Ethanol as a Model Compound
RSC Advances. 2014. V.4. N72. P.37964-37972. DOI: 10.1039/C4RA05948D WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 19 июн. 2014 г.
Принята к публикации: 12 авг. 2014 г.
Опубликована online: 12 авг. 2014 г.
Идентификаторы БД:
Web of science: WOS:000341455200001
Scopus: 2-s2.0-84906861374
РИНЦ: 23987443
Chemical Abstracts: 2014:1347188
Chemical Abstracts (print): 163:603144
OpenAlex: W2014446145
Цитирование в БД:
БД Цитирований
Web of science 7
Scopus 7
РИНЦ 9
OpenAlex 7
Альметрики: