Synthesis Gas Production from Bio-Oil: Steam Reforming of Ethanol as a Model Compound | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis Gas Production from Bio-Oil: Steam Reforming of Ethanol as a Model Compound Full article

Journal

RSC Advances
ISSN: 2046-2069

Output data

Year: 2014, Volume: 4, Number: 72, Pages: 37964-37972 Pages count : 9 DOI: 10.1039/C4RA05948D

Funding (2)

1	Russian Foundation for Basic Research	12-03-93115
2	Siberian Branch of the Russian Academy of Sciences	8

Using original hydrothermal technology honeycomb corundum monoliths with a peculiar porous structure and high water-adsorbing capacity facilitating procedures of active component loading have been produced. The detailed study of ethanol steam reforming over Ru/Ce0.5Zr0.5O2(CZ), Ru/Ce0.4Zr0.4Sm0.2O2–(δ + γ)Al2O3 (granulated) and Ru/Ce0.4Zr0.4Sm0.2O2/α-Al2O3 (monolithic) has been performed. It has been revealed that the main route of the reaction over Ru/CZ is ethanol dehydrogenation while ethanol dehydration into ethylene mainly occurs over Ru/CZS–Al2O3. Variation of the H2O–EtOH ratio, contact time and temperature allows hydrogen and CO yield to be governed. The monolithic catalyst has shown a high performance and stability at short contact time (0.1–0.4 s) and low water concentration (H2O–EtOH [similar] 1–3).

Pavlova S. , Yaseneva P. , Sadykov V. , Rogov V. , Tikhov S. , Bespalko Y. , Beloshapkin S. , Ross J.
Synthesis Gas Production from Bio-Oil: Steam Reforming of Ethanol as a Model Compound
RSC Advances. 2014. V.4. N72. P.37964-37972. DOI: 10.1039/C4RA05948D WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jun 19, 2014
Accepted:	Aug 12, 2014
Published online:	Aug 12, 2014

Web of science:	WOS:000341455200001
Scopus:	2-s2.0-84906861374
Elibrary:	23987443
Chemical Abstracts:	2014:1347188
Chemical Abstracts (print):	163:603144
OpenAlex:	W2014446145

DB	Citing
Web of science	7
Scopus	7
Elibrary	9
OpenAlex	7