Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks | Sciact - CRIS-система Института катализа

Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks Научная публикация

Журнал

Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691

Вых. Данные

Год: 2020, Том: 20, Номер: 11, Страницы: 1297-1313 Страниц : 18 DOI: 10.1002/tcr.202000072, 10.1002/tcr.202081101

Ключевые слова

Porous Coordination Polymers, Metal-Organic Frameworks, Proton Conductivity, Proton Dynamics, Conduction Mechanism

Авторы

Kolokolov Daniil I. ^1,2 , Lim Dae‐Woon ³ , Kitagawa Hiroshi ⁴

Организации

1	Siberian Branch of Russian Academy of Sciences, Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
2	Department of Physics, Novosibirsk State University, Pirogova Street 2, Novosibirsk 630090, Russia
3	Department of Chemistry and Medical Chemistry, Yonsei University, 1 Yonseidae-gil, Wonju, Gangwon-do, 26493, Korea
4	Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan

Информация о финансировании (3)

1	Japan Science and Technology Agency	JPMJAC1501
2	Федеральное агентство научных организаций России	0303-2016-0003
3	Российский фонд фундаментальных исследований	20-33-70141

Proton conductivity has been traditionally investigated with various materials such as organic polymers, metal oxides, and other inorganic and organic compounds because of their potential application in the electrochemical devices. In particular, during the last decade, crystalline porous coordination polymers (PCPs) or metal‐organic frameworks (MOFs) have received considerable attention in recent years, as solid‐state proton conductors (SSPCs). To date, proton‐conductive MOFs have achieved high performance in proton conductivity (>10−2 S cm−1) with rational design strategies. In addition, there are dedicated efforts to define the conduction pathway and mechanism using various experimental tools. In this review, we focus on the characterization of proton conductivity and molecular dynamics in hydrated MOFs, with selected examples to provide an understanding of the overall conduction mechanism.

Kolokolov D.I. , Lim D. , Kitagawa H.
Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks
Chemical Record. 2020. V.20. N11. P.1297-1313. DOI: 10.1002/tcr.202000072, 10.1002/tcr.202081101 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex

Поступила в редакцию:	18 июн. 2020 г.
Принята к публикации:	24 авг. 2020 г.
Опубликована online:	21 сент. 2020 г.
Опубликована в печати:	1 нояб. 2020 г.

Web of science:	WOS:000571436700001
Scopus:	2-s2.0-85091236777
РИНЦ:	45313139
Chemical Abstracts:	2020:1894853
Chemical Abstracts (print):	179:18868
PMID (PubMed):	32959508
OpenAlex:	W3087131247

БД	Цитирований
Scopus	59
Web of science	66
РИНЦ	58
OpenAlex	56