Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks Full article
| Journal |
Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691 |
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| Output data | Year: 2020, Volume: 20, Number: 11, Pages: 1297-1313 Pages count : 18 DOI: 10.1002/tcr.202000072 | ||||||||
| Tags | Porous Coordination Polymers, Metal-Organic Frameworks, Proton Conductivity, Proton Dynamics, Conduction Mechanism | ||||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 20-33-70141 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0003 |
| 3 | Japan Science and Technology Agency | JPMJAC1501 |
Abstract:
Proton conductivity has been traditionally investigated with various materials such as organic polymers, metal oxides, and other inorganic and organic compounds because of their potential application in the electrochemical devices. In particular, during the last decade, crystalline porous coordination polymers (PCPs) or metal‐organic frameworks (MOFs) have received considerable attention in recent years, as solid‐state proton conductors (SSPCs). To date, proton‐conductive MOFs have achieved high performance in proton conductivity (>10−2 S cm−1) with rational design strategies. In addition, there are dedicated efforts to define the conduction pathway and mechanism using various experimental tools. In this review, we focus on the characterization of proton conductivity and molecular dynamics in hydrated MOFs, with selected examples to provide an understanding of the overall conduction mechanism.
Cite:
Kolokolov D.I.
, Lim D.
, Kitagawa H.
Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks
Chemical Record. 2020. V.20. N11. P.1297-1313. DOI: 10.1002/tcr.202000072 WOS Scopus РИНЦ OpenAlex ANCAN PMID DOI (extra)
Characterization of Proton Dynamics for the Understanding of Conduction Mechanism in Proton Conductive Metal‐Organic Frameworks
Chemical Record. 2020. V.20. N11. P.1297-1313. DOI: 10.1002/tcr.202000072 WOS Scopus РИНЦ OpenAlex ANCAN PMID DOI (extra)
Dates:
| Submitted: | Jun 18, 2020 |
| Accepted: | Aug 24, 2020 |
| Published online: | Sep 21, 2020 |
| Published print: | Nov 1, 2020 |
Identifiers:
| ≡ Web of science: | WOS:000571436700001 |
| ≡ Scopus: | 2-s2.0-85091236777 |
| ≡ Elibrary: | 45313139 |
| ≡ OpenAlex: | W3087131247 |
| ≡ Chemical Abstracts: | 2020:1894853 |
| ≡ Chemical Abstracts (print): | 179:18868 |
| ≡ PMID: | 32959508 |
| ≡ DOI (extra): | 10.1002/tcr.202081101 |