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Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts Научная публикация

Журнал Journal of Energy Chemistry
ISSN: 2095-4956
Вых. Данные Год: 2013, Том: 22, Номер: 1, Страницы: 130-135 Страниц : 6 DOI: 10.1016/S2095-4956(13)60017-0
Ключевые слова Carbon dioxide, Cyclic carbonates, Cycloaddition, Heterogeneous catalysis, Metal-organic framework, Oxidative carboxylation, Quaternary ammonium salts
Авторы Zalomaeva Olga V. 1 , Maksimchuk Nataliya V. 1 , Chibiryaev Andrey M. 2 , Kovalenko Konstantin A. 3 , Fedin Vladimir P. 3 , Balzhinimaev Bair S. 1
Организации
1 Boreskov Institute of Catalysis, pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2 Vorozhtsov Novosibirsk Institute of Organic Chemistry, pr Akademika Lavrentieva, 9, Novosibirsk, 630090, Russia
3 Nikolaev Institute of Inorganic Chemistry, pr. Akademika Lavrentieva, 3, Novosibirsk, 630090, Russia

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 12-03-31537

Реферат: Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbonates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions (8 bar CO2, 25 C). Styrene and propylene carbonates were formed with high yields (95% and 82%, respectively). Catalytic performance of Cr-MIL-101 was compared with other MOFs: Fe-MIL-101, Zn-MOF-5 and HKUST-1. The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H2O2 as oxidants at 8−100 bar CO2 and 25−80 C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.
Библиографическая ссылка: Zalomaeva O.V. , Maksimchuk N.V. , Chibiryaev A.M. , Kovalenko K.A. , Fedin V.P. , Balzhinimaev B.S.
Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts
Journal of Energy Chemistry. 2013. V.22. N1. P.130-135. DOI: 10.1016/S2095-4956(13)60017-0 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 13 нояб. 2012 г.
Опубликована в печати: 1 янв. 2013 г.
Опубликована online: 15 апр. 2013 г.
Идентификаторы БД:
Web of science: WOS:000318050700018
Scopus: 2-s2.0-84879863964
РИНЦ: 20439657
Chemical Abstracts: 2013:1022220
OpenAlex: W2000724982
Цитирование в БД:
БД Цитирований
Web of science 79
Scopus 86
РИНЦ 76
OpenAlex 72
Альметрики: