Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts Научная публикация
Журнал |
Journal of Energy Chemistry
ISSN: 2095-4956 |
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Вых. Данные | Год: 2013, Том: 22, Номер: 1, Страницы: 130-135 Страниц : 6 DOI: 10.1016/S2095-4956(13)60017-0 | ||||||
Ключевые слова | Carbon dioxide, Cyclic carbonates, Cycloaddition, Heterogeneous catalysis, Metal-organic framework, Oxidative carboxylation, Quaternary ammonium salts | ||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 12-03-31537 |
Реферат:
Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbonates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions (8 bar CO2, 25 C). Styrene and propylene carbonates were formed with high yields (95% and 82%, respectively). Catalytic performance of Cr-MIL-101 was compared with other MOFs: Fe-MIL-101, Zn-MOF-5 and HKUST-1. The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl
hydroperoxide and H2O2 as oxidants at 8−100 bar CO2 and 25−80 C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.
Библиографическая ссылка:
Zalomaeva O.V.
, Maksimchuk N.V.
, Chibiryaev A.M.
, Kovalenko K.A.
, Fedin V.P.
, Balzhinimaev B.S.
Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts
Journal of Energy Chemistry. 2013. V.22. N1. P.130-135. DOI: 10.1016/S2095-4956(13)60017-0 WOS Scopus РИНЦ CAPlus OpenAlex
Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts
Journal of Energy Chemistry. 2013. V.22. N1. P.130-135. DOI: 10.1016/S2095-4956(13)60017-0 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: | 13 нояб. 2012 г. |
Опубликована в печати: | 1 янв. 2013 г. |
Опубликована online: | 15 апр. 2013 г. |
Идентификаторы БД:
Web of science: | WOS:000318050700018 |
Scopus: | 2-s2.0-84879863964 |
РИНЦ: | 20439657 |
Chemical Abstracts: | 2013:1022220 |
OpenAlex: | W2000724982 |