Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts Full article

Journal

Journal of Energy Chemistry
ISSN: 2095-4956

Output data

Year: 2013, Volume: 22, Number: 1, Pages: 130-135 Pages count : 6 DOI: 10.1016/S2095-4956(13)60017-0

Tags

Carbon dioxide, Cyclic carbonates, Cycloaddition, Heterogeneous catalysis, Metal-organic framework, Oxidative carboxylation, Quaternary ammonium salts

Authors

Zalomaeva Olga V. ¹ , Maksimchuk Nataliya V. ¹ , Chibiryaev Andrey M. ² , Kovalenko Konstantin A. ³ , Fedin Vladimir P. ³ , Balzhinimaev Bair S. ¹

Affiliations

1	Boreskov Institute of Catalysis, pr. Akademika Lavrentieva, 5, Novosibirsk 630090, Russia
2	Vorozhtsov Novosibirsk Institute of Organic Chemistry, pr Akademika Lavrentieva, 9, Novosibirsk, 630090, Russia
3	Nikolaev Institute of Inorganic Chemistry, pr. Akademika Lavrentieva, 3, Novosibirsk, 630090, Russia

Funding (1)

Russian Foundation for Basic Research

12-03-31537

Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbonates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions (8 bar CO2, 25 C). Styrene and propylene carbonates were formed with high yields (95% and 82%, respectively). Catalytic performance of Cr-MIL-101 was compared with other MOFs: Fe-MIL-101, Zn-MOF-5 and HKUST-1. The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H2O2 as oxidants at 8−100 bar CO2 and 25−80 C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.

Zalomaeva O.V. , Maksimchuk N.V. , Chibiryaev A.M. , Kovalenko K.A. , Fedin V.P. , Balzhinimaev B.S.
Synthesis of Cyclic Carbonates from Epoxides or Olefins and CO2 Catalyzed by Metal-Organic Frameworks and Quaternary Ammonium Salts
Journal of Energy Chemistry. 2013. V.22. N1. P.130-135. DOI: 10.1016/S2095-4956(13)60017-0 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Nov 13, 2012
Published print:	Jan 1, 2013
Published online:	Apr 15, 2013

Web of science:	WOS:000318050700018
Scopus:	2-s2.0-84879863964
Elibrary:	20439657
Chemical Abstracts:	2013:1022220
OpenAlex:	W2000724982

DB	Citing
Web of science	83
Scopus	90
Elibrary	83
OpenAlex	82