Catalytic Performance of Ru/Polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol | Sciact - CRIS-система Института катализа

Catalytic Performance of Ru/Polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol Научная публикация

Журнал

Chemical Engineering Transactions
ISSN: 1974-9791

Вых. Данные

Год: 2020, Том: 81, Страницы: 1231-1236 Страниц : 6 DOI: 10.3303/CET2081206

Авторы

Sulman Mikhail ¹ , Matveeva Valentina ^1,2 , Salnikova Ksenia ² , Larichev Yurii ^3,4 , Mikhailov Stepan ² , Bykov Alexey ¹ , Demidenko Galina ¹ , Sidorov Alexander ¹ , Sulman Esther ¹

Организации

1	Tver State Technical University, Dept. Of Biotechnology and chemistry, A.Nikitin str., 22, 170026 Tver, Russia
2	Tver State University, Regional technological center, Zhelyabova str., 33, 170100 Tver, Russia
3	Boreskov Institute of Catalysis, 5 Academician Lavrentiev Avenue, 630090 Novosibirsk, Russia
4	Novosibirsk State University, 2 Pirogov Street, 630090 Novosibirsk, Russia

Информация о финансировании (2)

1	Российский научный фонд	19-19-00490 (АААА-А20-120022190099-1)
2	Российский фонд фундаментальных исследований	20-08-00433

Furfural (FF) is one of the main components of bio-oil obtained by the treatment of lignocellulose biomass. Furfural alcohol (FA) as the main product of the selective FF hydrogenation is a source of value-added chemicals. In this paper, the results of the study of ruthenium catalysts based on hyper-crosslinked polystyrene (PS) in the selective hydrogenation of FF to FA are presented. Two types of ruthenium catalysts: nanoparticles of RuO2 and Ru0 stabilized in the PS pores were synthesized and compared. The novelty of this work is in the comparison of the PS stabilized Ru0 and RuO2 nanoparticles were performed and differences in their catalytic properties were shown. The BET, TEM, and SAXS data showed the formation of Ru-containing nanoparticles similar in size and structure for both catalysts. The comparison of the catalytic properties of the Ru catalysts showed that the catalyst with Ru0 (Ru-PS) exhibits higher values of FF conversion (99 %) and selectivity to FA (96 %). It can be assumed that Ru0 nanoparticles are responsible for the formation of catalytically active sites of selective hydrogenation of FF to FA. © 2020 Italian Association of Chemical Engineering - AIDIC. All rights reserved.

Sulman M. , Matveeva V. , Salnikova K. , Larichev Y. , Mikhailov S. , Bykov A. , Demidenko G. , Sidorov A. , Sulman E.
Catalytic Performance of Ru/Polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol
Chemical Engineering Transactions. 2020. V.81. P.1231-1236. DOI: 10.3303/CET2081206 Scopus РИНЦ OpenAlex

Поступила в редакцию:	31 мар. 2020 г.
Принята к публикации:	27 июн. 2020 г.

Scopus:	2-s2.0-85092066038
РИНЦ:	45249697
OpenAlex:	W3110439858

БД	Цитирований
Scopus	2
РИНЦ	3
OpenAlex	1