Catalytic Performance of Ru/Polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Performance of Ru/Polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol Full article

Journal

Chemical Engineering Transactions
ISSN: 1974-9791

Output data

Year: 2020, Volume: 81, Pages: 1231-1236 Pages count : 6 DOI: 10.3303/CET2081206

Authors

Sulman Mikhail ¹ , Matveeva Valentina ^1,2 , Salnikova Ksenia ² , Larichev Yurii ^3,4 , Mikhailov Stepan ² , Bykov Alexey ¹ , Demidenko Galina ¹ , Sidorov Alexander ¹ , Sulman Esther ¹

Affiliations

1	Tver State Technical University, Dept. Of Biotechnology and chemistry, A.Nikitin str., 22, 170026 Tver, Russia
2	Tver State University, Regional technological center, Zhelyabova str., 33, 170100 Tver, Russia
3	Boreskov Institute of Catalysis, 5 Academician Lavrentiev Avenue, 630090 Novosibirsk, Russia
4	Novosibirsk State University, 2 Pirogov Street, 630090 Novosibirsk, Russia

Funding (2)

1	Russian Science Foundation	19-19-00490 (АААА-А20-120022190099-1)
2	Russian Foundation for Basic Research	20-08-00433

Furfural (FF) is one of the main components of bio-oil obtained by the treatment of lignocellulose biomass. Furfural alcohol (FA) as the main product of the selective FF hydrogenation is a source of value-added chemicals. In this paper, the results of the study of ruthenium catalysts based on hyper-crosslinked polystyrene (PS) in the selective hydrogenation of FF to FA are presented. Two types of ruthenium catalysts: nanoparticles of RuO2 and Ru0 stabilized in the PS pores were synthesized and compared. The novelty of this work is in the comparison of the PS stabilized Ru0 and RuO2 nanoparticles were performed and differences in their catalytic properties were shown. The BET, TEM, and SAXS data showed the formation of Ru-containing nanoparticles similar in size and structure for both catalysts. The comparison of the catalytic properties of the Ru catalysts showed that the catalyst with Ru0 (Ru-PS) exhibits higher values of FF conversion (99 %) and selectivity to FA (96 %). It can be assumed that Ru0 nanoparticles are responsible for the formation of catalytically active sites of selective hydrogenation of FF to FA. © 2020 Italian Association of Chemical Engineering - AIDIC. All rights reserved.

Sulman M. , Matveeva V. , Salnikova K. , Larichev Y. , Mikhailov S. , Bykov A. , Demidenko G. , Sidorov A. , Sulman E.
Catalytic Performance of Ru/Polymer Catalyst in the Hydrogenation of Furfural to Furfuryl Alcohol
Chemical Engineering Transactions. 2020. V.81. P.1231-1236. DOI: 10.3303/CET2081206 Scopus РИНЦ OpenAlex

Submitted:	Mar 31, 2020
Accepted:	Jun 27, 2020

Scopus:	2-s2.0-85092066038
Elibrary:	45249697
OpenAlex:	W3110439858

DB	Citing
Scopus	2
Elibrary	3
OpenAlex	1