Solid-State NaBH4 Composites for Hydrogen Generation: Catalytic Activity of Nickel and Cobalt Catalysts Научная публикация
| Журнал |
International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2021, Том: 46, Номер: 7, Страницы: 5459-5471 Страниц : 13 DOI: 10.1016/j.ijhydene.2020.11.078 | ||||
| Ключевые слова | Sodium borohydride; Hydrolysis; Cobalt; Nickel; Catalyst; Kinetics | ||||
| Авторы |
|
||||
| Организации |
|
Информация о финансировании (2)
| 1 | Российский фонд фундаментальных исследований | 19-08-00599 |
| 2 | Федеральное агентство научных организаций России | 0303-2016-0015 |
Реферат:
Hydrogen generation from tablets of sodium borohydride with chlorides of nickel and cobalt was studied. The nickel catalysts were shown to be less active in the borohydride hydrolysis than the cobalt catalysts. One of the reasons for the lower activity of the nickel catalyst was the presence of hydrogen on its surface, which hampered the adsorption of reactants. The addition of cobalt to the nickel catalyst increases the hydrogen generation rate. This is due to the introduction of active metal with low adsorption capacity for hydrogen and the higher dispersion of the active component
Библиографическая ссылка:
Netskina O.V.
, Tayban E.S.
, Rogov V.A.
, Ozerova A.M.
, Mukha S.A.
, Simagina V.I.
, Komova O.V.
Solid-State NaBH4 Composites for Hydrogen Generation: Catalytic Activity of Nickel and Cobalt Catalysts
International Journal of Hydrogen Energy. 2021. V.46. N7. P.5459-5471. DOI: 10.1016/j.ijhydene.2020.11.078 WOS Scopus РИНЦ OpenAlex CAPlus
Solid-State NaBH4 Composites for Hydrogen Generation: Catalytic Activity of Nickel and Cobalt Catalysts
International Journal of Hydrogen Energy. 2021. V.46. N7. P.5459-5471. DOI: 10.1016/j.ijhydene.2020.11.078 WOS Scopus РИНЦ OpenAlex CAPlus
Даты:
| Поступила в редакцию: | 8 сент. 2020 г. |
| Принята к публикации: | 8 нояб. 2020 г. |
| Опубликована online: | 4 дек. 2020 г. |
| Опубликована в печати: | 27 янв. 2021 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000608630000016 |
| ≡ Scopus: | 2-s2.0-85097238117 |
| ≡ РИНЦ: | 45106092 |
| ≡ OpenAlex: | W3110018728 |
| ≡ Chemical Abstracts: | 2020:2446479 |