Solid-State NaBH4 Composites for Hydrogen Generation: Catalytic Activity of Nickel and Cobalt Catalysts Full article
| Journal |
International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487 |
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| Output data | Year: 2021, Volume: 46, Number: 7, Pages: 5459-5471 Pages count : 13 DOI: 10.1016/j.ijhydene.2020.11.078 | ||||
| Tags | Sodium borohydride; Hydrolysis; Cobalt; Nickel; Catalyst; Kinetics | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 19-08-00599 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0015 |
Abstract:
Hydrogen generation from tablets of sodium borohydride with chlorides of nickel and cobalt was studied. The nickel catalysts were shown to be less active in the borohydride hydrolysis than the cobalt catalysts. One of the reasons for the lower activity of the nickel catalyst was the presence of hydrogen on its surface, which hampered the adsorption of reactants. The addition of cobalt to the nickel catalyst increases the hydrogen generation rate. This is due to the introduction of active metal with low adsorption capacity for hydrogen and the higher dispersion of the active component
Cite:
Netskina O.V.
, Tayban E.S.
, Rogov V.A.
, Ozerova A.M.
, Mukha S.A.
, Simagina V.I.
, Komova O.V.
Solid-State NaBH4 Composites for Hydrogen Generation: Catalytic Activity of Nickel and Cobalt Catalysts
International Journal of Hydrogen Energy. 2021. V.46. N7. P.5459-5471. DOI: 10.1016/j.ijhydene.2020.11.078 WOS Scopus РИНЦ OpenAlex AN
Solid-State NaBH4 Composites for Hydrogen Generation: Catalytic Activity of Nickel and Cobalt Catalysts
International Journal of Hydrogen Energy. 2021. V.46. N7. P.5459-5471. DOI: 10.1016/j.ijhydene.2020.11.078 WOS Scopus РИНЦ OpenAlex AN
Dates:
| Submitted: | Sep 8, 2020 |
| Accepted: | Nov 8, 2020 |
| Published online: | Dec 4, 2020 |
| Published print: | Jan 27, 2021 |
Identifiers:
| ≡ Web of science: | WOS:000608630000016 |
| ≡ Scopus: | 2-s2.0-85097238117 |
| ≡ Elibrary: | 45106092 |
| ≡ OpenAlex: | W3110018728 |
| ≡ Chemical Abstracts: | 2020:2446479 |