Kinetics of Phenol Hydrogenation over Pd-Containing Hypercrosslinked Polystyrene | Sciact - CRIS-система Института катализа

Kinetics of Phenol Hydrogenation over Pd-Containing Hypercrosslinked Polystyrene Научная публикация

Конференция

XIX International Conference on Chemical Reactors
05-09 сент. 2010 , Vienna

Журнал

Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212

Вых. Данные

Год: 2011, Том: 176-177, Страницы: 33-41 Страниц : 9 DOI: 10.1016/j.cej.2011.05.044

Ключевые слова

Cyclohexanone, Hypercrosslinked polysterene, Palladium, Phenol, Phenol hydrogenation, Selective hydrogenation kinetics

Авторы

Sulman E.M. ¹ , Ivanov A.A. ² , Chernyavsky V.S. ² , Sulman M.G. ¹ , Bykov A.I. ¹ , Sidorov A.I. ¹ , Doluda V.Y. ¹ , Matveeva V.G. ¹ , Bronstein L.M. ³ , Stein B. ⁴ , Kharitonov A.S. ²

Организации

1	Tver Technical University, Tver, Russia
2	Boreskov Institute of Catalysis SB RAS, Pr. Ak. Lavrentieva 5, Novosibirsk, 630090, Russia
3	Indiana University, Department of Chemistry, Bloomington, IN, USA
4	Indiana University, Department of Biology, Bloomington, IN, USA

Информация о финансировании (3)

1	Министерство образования и науки Российской Федерации	02.552.11.7075
2	Министерство образования и науки Российской Федерации	02.740.11.0145
3	Министерство образования и науки Российской Федерации	02.740.11.5104

Hypercrosslinked polystyrene (HPS) has been used as a support for preparation of the palladium-based catalyst, Pd/HPS, for gas phase hydrogenation of phenol to cyclohexanone. At the phenol conversion 99%, the catalyst provides selectivity for ketone not lower than 95 mol%. The Pd/HPS catalyst showed high stability, retaining its catalytic performance at least for 20 days. Kinetics was used to compare Pd/HPS with the commercial Pd/Al2O3 catalyst. The catalytic efficiency was assessed using the derived dimensionless kinetic equation without a ‘time’ parameter. Three major reaction routes with their rate parameters and activation energies were revealed. From kinetic parameters, the maximum possible yield of cyclohexanone in the temperature range of 120–180 °C was determined. The important feature of the Pd/HPS catalyst is that selectivity is independent of the temperature at a certain phenol conversion. At elevated temperatures (160–180 °C), the selectivity is at least 2–3% higher as compared to the commercial catalyst Pd/Al2O3, which makes Pd/HPS largely promising for industrial applications.

Sulman E.M. , Ivanov A.A. , Chernyavsky V.S. , Sulman M.G. , Bykov A.I. , Sidorov A.I. , Doluda V.Y. , Matveeva V.G. , Bronstein L.M. , Stein B. , Kharitonov A.S.
Kinetics of Phenol Hydrogenation over Pd-Containing Hypercrosslinked Polystyrene
Chemical Engineering Journal. 2011. V.176-177. P.33-41. DOI: 10.1016/j.cej.2011.05.044 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	2 дек. 2010 г.
Принята к публикации:	11 мая 2011 г.
Опубликована online:	19 мая 2011 г.
Опубликована в печати:	1 дек. 2011 г.

Web of science:	WOS:000298900200006
Scopus:	2-s2.0-81555216742
РИНЦ:	20520145
Chemical Abstracts:	2011:1493072
Chemical Abstracts (print):	155:639264
OpenAlex:	W2030770449

БД	Цитирований
Web of science	27
Scopus	26
РИНЦ	28
OpenAlex	27