Kinetics of Phenol Hydrogenation over Pd-Containing Hypercrosslinked Polystyrene Full article
| Conference |
XIX International Conference on Chemical Reactors 05-09 Sep 2010 , Vienna |
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| Journal |
Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212 |
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| Output data | Year: 2011, Volume: 176-177, Pages: 33-41 Pages count : 9 DOI: 10.1016/j.cej.2011.05.044 | ||||||||
| Tags | Cyclohexanone, Hypercrosslinked polysterene, Palladium, Phenol, Phenol hydrogenation, Selective hydrogenation kinetics | ||||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | The Ministry of Education and Science of the Russian Federation | 02.552.11.7075 |
| 2 | The Ministry of Education and Science of the Russian Federation | 02.740.11.0145 |
| 3 | The Ministry of Education and Science of the Russian Federation | 02.740.11.5104 |
Abstract:
Hypercrosslinked polystyrene (HPS) has been used as a support for preparation of the palladium-based catalyst, Pd/HPS, for gas phase hydrogenation of phenol to cyclohexanone. At the phenol conversion 99%, the catalyst provides selectivity for ketone not lower than 95 mol%. The Pd/HPS catalyst showed high stability, retaining its catalytic performance at least for 20 days. Kinetics was used to compare Pd/HPS with the commercial Pd/Al2O3 catalyst. The catalytic efficiency was assessed using the derived dimensionless kinetic equation without a ‘time’ parameter. Three major reaction routes with their rate parameters and activation energies were revealed. From kinetic parameters, the maximum possible yield of cyclohexanone in the temperature range of 120–180 °C was determined. The important feature of the Pd/HPS catalyst is that selectivity is independent of the temperature at a certain phenol conversion. At elevated temperatures (160–180 °C), the selectivity is at least 2–3% higher as compared to the commercial catalyst Pd/Al2O3, which makes Pd/HPS largely promising for industrial applications.
Cite:
Sulman E.M.
, Ivanov A.A.
, Chernyavsky V.S.
, Sulman M.G.
, Bykov A.I.
, Sidorov A.I.
, Doluda V.Y.
, Matveeva V.G.
, Bronstein L.M.
, Stein B.
, Kharitonov A.S.
Kinetics of Phenol Hydrogenation over Pd-Containing Hypercrosslinked Polystyrene
Chemical Engineering Journal. 2011. V.176-177. P.33-41. DOI: 10.1016/j.cej.2011.05.044 WOS Scopus РИНЦ ANCAN OpenAlex
Kinetics of Phenol Hydrogenation over Pd-Containing Hypercrosslinked Polystyrene
Chemical Engineering Journal. 2011. V.176-177. P.33-41. DOI: 10.1016/j.cej.2011.05.044 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Dec 2, 2010 |
| Accepted: | May 11, 2011 |
| Published online: | May 19, 2011 |
| Published print: | Dec 1, 2011 |
Identifiers:
| Web of science: | WOS:000298900200006 |
| Scopus: | 2-s2.0-81555216742 |
| Elibrary: | 20520145 |
| Chemical Abstracts: | 2011:1493072 |
| Chemical Abstracts (print): | 155:639264 |
| OpenAlex: | W2030770449 |