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The Effect of Composition of the Ruthenium Precursors and Heat Treatment Conditions on the Activity of Ru-Ba/Sibunit Catalysts for Ammonia Synthesis Научная публикация

Журнал Molecular Catalysis
ISSN: 2468-8231
Вых. Данные Год: 2017, Том: 433, Страницы: 235-241 Страниц : 7 DOI: 10.1016/j.mcat.2016.12.015
Ключевые слова Ammonia synthesis; Supported ruthenium catalysts; Barium promoter; Sibunit
Авторы Smirnova N.S. 3 , Iost K.N. 1 , Temerev V.L. 1 , Gulyaeva T.I. 1 , Trenikhin M.V. 1 , Muromtsev I.V. 1 , Khramov E.V. 2 , Zubavichus Y.V. 2 , Shlyapin D.A. 1 , Tsyrul’nikov P.G. 1
Организации
1 Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya st., 54, Omsk 644040, Russia
2 National Research Center “Kurchatov Institute”, pl. Kurchatova, 1, Moscow 123182, Russia
3 Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prospect, 31, Moscow 119991, Russia

Реферат: The effect of composition of the chlorine-containing precursors of ruthenium and heat treatment conditions on the preparation of catalysts supported on carbon composite Sibunit for the ammonia synthesis was studied. The activity of Ru-Ba/Sibunit samples was shown to depend on ruthenium dispersion and residual chlorine content in the catalyst. The removal of outer-sphere chloride ions from ammonia complexes of ruthenium via ionic exchange and the replacement of hydrogen reduction of the Ru precursor by calcination in an inert atmosphere prevent sintering and agglomeration of the active component particles, thus enhancing the catalyst activity.
Библиографическая ссылка: Smirnova N.S. , Iost K.N. , Temerev V.L. , Gulyaeva T.I. , Trenikhin M.V. , Muromtsev I.V. , Khramov E.V. , Zubavichus Y.V. , Shlyapin D.A. , Tsyrul’nikov P.G.
The Effect of Composition of the Ruthenium Precursors and Heat Treatment Conditions on the Activity of Ru-Ba/Sibunit Catalysts for Ammonia Synthesis
Molecular Catalysis. 2017. V.433. P.235-241. DOI: 10.1016/j.mcat.2016.12.015 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 2 авг. 2016 г.
Принята к публикации: 21 дек. 2016 г.
Опубликована online: 1 апр. 2017 г.
Опубликована в печати: 1 мая 2017 г.
Идентификаторы БД:
Web of science: WOS:000400562600029
Scopus: 2-s2.0-85029622047
РИНЦ: 31058996
Chemical Abstracts: 2017:1491060
Chemical Abstracts (print): 168:457029
OpenAlex: W2598220475
Цитирование в БД:
БД Цитирований
Web of science 8
Scopus 8
РИНЦ 8
OpenAlex 9
Альметрики: