The Effect of Composition of the Ruthenium Precursors and Heat Treatment Conditions on the Activity of Ru-Ba/Sibunit Catalysts for Ammonia Synthesis | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Effect of Composition of the Ruthenium Precursors and Heat Treatment Conditions on the Activity of Ru-Ba/Sibunit Catalysts for Ammonia Synthesis Full article

Journal

Molecular Catalysis
ISSN: 2468-8231

Output data

Year: 2017, Volume: 433, Pages: 235-241 Pages count : 7 DOI: 10.1016/j.mcat.2016.12.015

Tags

Ammonia synthesis; Supported ruthenium catalysts; Barium promoter; Sibunit

Authors

Smirnova N.S. ³ , Iost K.N. ¹ , Temerev V.L. ¹ , Gulyaeva T.I. ¹ , Trenikhin M.V. ¹ , Muromtsev I.V. ¹ , Khramov E.V. ² , Zubavichus Y.V. ² , Shlyapin D.A. ¹ , Tsyrul’nikov P.G. ¹

Affiliations

1	Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya st., 54, Omsk 644040, Russia
2	National Research Center “Kurchatov Institute”, pl. Kurchatova, 1, Moscow 123182, Russia
3	Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prospect, 31, Moscow 119991, Russia

The effect of composition of the chlorine-containing precursors of ruthenium and heat treatment conditions on the preparation of catalysts supported on carbon composite Sibunit for the ammonia synthesis was studied. The activity of Ru-Ba/Sibunit samples was shown to depend on ruthenium dispersion and residual chlorine content in the catalyst. The removal of outer-sphere chloride ions from ammonia complexes of ruthenium via ionic exchange and the replacement of hydrogen reduction of the Ru precursor by calcination in an inert atmosphere prevent sintering and agglomeration of the active component particles, thus enhancing the catalyst activity.

Smirnova N.S. , Iost K.N. , Temerev V.L. , Gulyaeva T.I. , Trenikhin M.V. , Muromtsev I.V. , Khramov E.V. , Zubavichus Y.V. , Shlyapin D.A. , Tsyrul’nikov P.G.
The Effect of Composition of the Ruthenium Precursors and Heat Treatment Conditions on the Activity of Ru-Ba/Sibunit Catalysts for Ammonia Synthesis
Molecular Catalysis. 2017. V.433. P.235-241. DOI: 10.1016/j.mcat.2016.12.015 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 2, 2016
Accepted:	Dec 21, 2016
Published online:	Apr 1, 2017
Published print:	May 1, 2017

Web of science:	WOS:000400562600029
Scopus:	2-s2.0-85029622047
Elibrary:	31058996
Chemical Abstracts:	2017:1491060
Chemical Abstracts (print):	168:457029
OpenAlex:	W2598220475

DB	Citing
Web of science	8
Scopus	8
Elibrary	8
OpenAlex	9